发明授权
- 专利标题: Homogeneous olefin polymerization catalyst by abstraction with lewis acids
- 专利标题(中): 均相烯烃聚合催化剂与路易斯酸的萃取
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申请号: US876268申请日: 1992-05-05
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公开(公告)号: US5721185A公开(公告)日: 1998-02-24
- 发明人: Robert E. LaPointe , James C. Stevens , Peter N. Nickias , Mark H. McAdon
- 申请人: Robert E. LaPointe , James C. Stevens , Peter N. Nickias , Mark H. McAdon
- 申请人地址: MI Midland
- 专利权人: The Dow Chemical Company
- 当前专利权人: The Dow Chemical Company
- 当前专利权人地址: MI Midland
- 主分类号: C08F4/60
- IPC分类号: C08F4/60 ; C07F17/00 ; C08F4/42 ; C08F4/64 ; C08F4/643 ; C08F4/659 ; C08F4/6592 ; C08F4/74 ; C08F10/00 ; C08F110/02 ; C08F110/06 ; C08F210/06 ; C08F210/16 ; B01J31/00
摘要:
A process for preparing addition polymerization catalysts having a limiting charge separated structure corresponding to the formula: LMX.sup.+ XA.sup.-, wherein: L is a derivative of a substituted delocalized .pi.-bonded group imparting a constrained geometry to the metal active site and containing up to 50 nonhydrogen atoms; M is a metal of Group 4 or the Lanthanide series of the Periodic Table of the Elements; X independently each occurrence is hydride or a hydrocarbyl, silyl or germyl group having up to 20 carbon, silicon or germanium atoms; and A.sup.- is an anion of a Lewis acid, A, having relative Lewis acidity greater than or equal to that of phenylbis(perfluorophenyl)borane, said anion being compatible with the metal cation, the steps of the process comprising contacting a derivative of a Group 4 or Lanthanide metal corresponding to the formula: i LMX.sub.2, wherein L, M, and X are as previously defined, with the Lewis acid, A, under conditions to cause abstraction of X and formation of the anion XA.sup.-.