发明授权
- 专利标题: Supported catalyst
- 专利标题(中): 负载催化剂
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申请号: US643102申请日: 1996-05-02
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公开(公告)号: US5744417A公开(公告)日: 1998-04-28
- 发明人: Sandor Nagy , John A. Tyrell
- 申请人: Sandor Nagy , John A. Tyrell
- 申请人地址: TX Houston
- 专利权人: Lyondell Petrochemical Company
- 当前专利权人: Lyondell Petrochemical Company
- 当前专利权人地址: TX Houston
- 主分类号: C08F4/606
- IPC分类号: C08F4/606 ; C08F4/609 ; C08F4/64 ; C08F4/659 ; C08F4/6592 ; C08F10/00
摘要:
Disclosed is a supported catalyst which is the reaction product of (a) a silylamine polymer having the general formula ##STR1## where each R is independently selected from alkyl from C.sub.1 to C.sub.6 or aryl from C.sub.6 to C.sub.10, R.sub.1 is a divalent aliphatic or aromatic group from C.sub.2 to C.sub.20, "m" is 1 to about 100, and "n" is 2 to about 500, with (b) an organometallic compound having the general formula Q--M--(X).sub.3 where Q is a stabilizing ligand, each X is independently selected from halogen, alkyl from C.sub.1 to C.sub.6, or dialkylamino from C.sub.1 to C.sub.6, M is zirconium, titanium, or hafnium and M is bonded to a nitrogen in said silylamine polymer, and the ratio nitrogens bondable to M in said silylamine polymer to M atoms is 1:1 to 3:1.