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公开(公告)号：US06967184B2
公开(公告)日：2005-11-22
申请号：US10780438
申请日：2004-02-17
CPC分类号： C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
摘要： A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 14 to Group 16 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
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2.发明授权Chromium support-agglomerate-transition metal polymerization catalysts and processes utilizing same 有权铬载体 - 附聚物 - 过渡金属聚合催化剂及其利用方法公开(公告)号：US06958375B2
公开(公告)日：2005-10-25
申请号：US10120310
申请日：2002-04-10
CPC分类号： C08F110/02 , C08F4/606 , C08F2410/04 , C08F4/70 , C08F4/69 , C08F4/025 , C08F2500/01 , C08F2500/12 , C08F2500/18
摘要： The present invention is directed to a novel one-step method for forming a supported catalyst complex of high activity by substantially simultaneously contacting a bidentate or tridentate ligand forming compound, a transition metal compound and a chromium immobilized Lewis acid support-agglomerate. The catalyst can be formed prior to polymerization of olefins or within the polymerization reaction zone.
摘要翻译： 本发明涉及通过基本上同时接触二齿或三齿配体形成化合物，过渡金属化合物和固定有铬的路易斯酸载体 - 附聚物来形成具有高活性的负载型催化剂络合物的新型一步法。 催化剂可以在烯烃聚合之前或在聚合反应区内形成。
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3.发明授权Polymerization catalyst compositions and processes to produce polymers and bimodal polymers 有权聚合催化剂组合物和生产聚合物和双峰聚合物的方法公开(公告)号：US06936667B2
公开(公告)日：2005-08-30
申请号：US10348033
申请日：2003-01-21
申请人： Michael D. Jensen , Max P. McDaniel , Elizabeth A. Benham , Anthony P. Eaton , Joel L. Martin , Gil R. Hawley , Tony R. Crain , Martha J. Tanner
发明人： Michael D. Jensen , Max P. McDaniel , Elizabeth A. Benham , Anthony P. Eaton , Joel L. Martin , Gil R. Hawley , Tony R. Crain , Martha J. Tanner
IPC分类号： C08F4/606 , C08F4/02 , C08F4/6192 , C08F4/655 , C08F4/658 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/64
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F2410/01 , Y10S526/943 , C08F4/6592 , C08F2500/12 , C08F210/14 , C08F2500/05
摘要： A process to produce a first catalyst composition is provided. The process comprises contacting at least one first organometal compound and at least one activator to produce the first catalyst composition. The activator is selected from the group consisting of aluminoxanes, fluoro-organo borates, and treated solid oxide components in combination with at least one organoaluminum compound. In another embodiment of this invention, a process to produce a second catalyst composition for producing bimodal polymers is provided. The process comprises contacting at least one first organometal compound, at least one activator, and at least one second organometal compound to produce the second catalyst composition. The first and second catalyst compositions are also provided as well as polymerization processes using these compositions to produce polymers.
摘要翻译： 提供了生产第一催化剂组合物的方法。 该方法包括使至少一种第一有机金属化合物和至少一种活化剂接触以产生第一催化剂组合物。 活化剂选自铝氧烷，氟代有机硼酸盐和经处理的固体氧化物组分与至少一种有机铝化合物的组合。 在本发明的另一个实施方案中，提供了制备用于生产双峰聚合物的第二催化剂组合物的方法。 该方法包括使至少一种第一有机金属化合物，至少一种活化剂和至少一种第二有机金属化合物接触以产生第二催化剂组合物。 还提供了第一和第二催化剂组合物以及使用这些组合物生产聚合物的聚合方法。
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4.发明授权
公开(公告)号：US6031058A
公开(公告)日：2000-02-29
申请号：US263930
申请日：1999-03-08
CPC分类号： C08F32/08
摘要： Silyl substituted polymers of polycycloolefins are provided as well as catalyst systems for their preparation. The polymers of the invention include polycyclic repeat units that contain pendant silyl functional groups represented by the following formulae: ##STR1## wherein A is a divalent radical selected from the following structures: ##STR2## R.sup.9 independently represents hydrogen, methyl, or ethyl; R.sup.10, R.sup.11, and R.sup.12 independently represent halogen, linear or branched (C.sub.1 to C.sub.20) alkyl, linear or branched (C.sub.1 to C.sub.20) alkoxy, linear or branched (C.sub.1 to C.sub.20) alkyl carbonyloxy, (C.sub.1 to C.sub.20) alkyl peroxy, and substituted or unsubstituted (C.sub.6 to C.sub.20) aryloxy; R.sup.10, R.sup.11, and R.sup.12 together with the silicon atom to which they are attached form the group: ##STR3## n is a number from 0 to 5; and n' is 0 or 1; and n" is a number from 0 to 10.
摘要翻译： 提供聚环烯烃的甲硅烷基取代聚合物以及用于其制备的催化剂体系。 本发明的聚合物包括含有由下式表示的侧链甲硅烷基官能团的多环重复单元：其中A是选自以下结构的二价基团：R9独立地表示氢，甲基或乙基; R10，R11和R12独立地表示直链或支链（C1至C20）烷基，直链或支链（C1至C20）烷氧基，直链或支链（C1至C20）烷基羰基氧基，（C1至C20）烷基过氧基），和 取代或未取代的（C6〜C20）芳氧基; R 10，R 11和R 12与它们所连接的硅原子一起形成基团：n为0至5的数; 并且n'为0或1; n“是从0到10的数字。
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公开(公告)号：US5912313A
公开(公告)日：1999-06-15
申请号：US562345
申请日：1995-11-22
IPC分类号： C08F4/605 , C08F4/606 , C08F32/08 , C08F232/08 , C08F230/08
CPC分类号： C08F32/08
摘要： Silyl substituted polymers of polycycloolefins are provided as well as catalyst systems for their preparation. The polymers of the invention include polycyclic repeat units that contain pendant silyl functional groups represented by the following formulae: ##STR1## wherein A is a divalent radical selected from the following structures: ##STR2## R.sup.9 independently represents hydrogen, methyl, or ethyl; R.sup.10, R.sup.11, and R.sup.12 independently represent halogen, linear or branched (C.sub.1 to C.sub.20) alkyl, linear or branched (C.sub.1 to C.sub.20) alkoxy, linear or branched (C.sub.1 to C.sub.20) alkyl carbonyloxy, (C.sub.1 to C.sub.20) alkyl peroxy, and substituted or unsubstituted (C.sub.6 to C.sub.20) aryloxy; R.sup.10, R.sup.11, and R.sup.12 together with the silicon atom to which they are attached form the group: ##STR3## n is a number from 0 to 5; and n' is 0 or 1; and n" is a number from 0 to 10.
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6.发明授权Olefin polymerization catalyst comprising a metallocene and an anhydrous lithium halide-treated alkylaluminoxane 失效烯烃聚合催化剂包含茂金属和无水卤化锂处理的烷基铝氧烷
公开(公告)号：US5565397A
公开(公告)日：1996-10-15
申请号：US440037
申请日：1995-05-12
申请人： Samuel A. Sangokoya
发明人： Samuel A. Sangokoya
摘要： Alkylaluminoxanes having improved catalytic activity such as when they are used in combination with metallocenes for the polymerization of alpha-olefins, are prepared by treating an organic solvent solution of an alkylaluminoxane, such as methylaluminoxane, with anhydrous lithium halide.
摘要翻译： 通过用无水卤化锂处理烷基铝氧烷如甲基铝氧烷的有机溶剂溶液制备具有改善的催化活性的烷基铝氧烷，例如当它们与金属茂组合用于α-烯烃的聚合时。
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公开(公告)号：US5077255A
公开(公告)日：1991-12-31
申请号：US906103
申请日：1986-09-10
IPC分类号： C08F4/64 , C08F4/60 , C08F4/606 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/685 , C08F10/00 , C08F210/00 , C08F4/648 , C08F10/02
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： An olefin polymerization supported catalyst comprising the supported reaction product of at least one metallocene of a metal of Group IVB, VB, and VIB of the Periodic Table, a non-metallocene transition metal containing compound of a Group IBV, VB, or VIB metal and an alumoxane, said reaction product formed in the presence of the support. The supported product is highly useful for the polymerization of olefins especially ethylene and especially for the copolymerization of ethylene and other mono and diolefins.
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公开(公告)号：US20100216957A1
公开(公告)日：2010-08-26
申请号：US12521104
申请日：2007-12-28
申请人： Anssi Haikarainen , Peter Denifl , Timo Leinonen
发明人： Anssi Haikarainen , Peter Denifl , Timo Leinonen
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12
摘要： The invention refers to a process for preparing a Group 2 metal/transition metal olefin polymerization catalyst component in particulate form having an improved polymerisation properties due to the addition of a phosphorous compound during catalyst component preparation and the use thereof in a process for polymerising olefins.
摘要翻译： 本发明是指由于在催化剂组分制备过程中加入磷化合物及其在烯烃聚合方法中的应用而制备具有改进聚合性能的颗粒形式的第2族金属/过渡金属烯烃聚合催化剂组分的方法。
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9.发明授权Fluoralcohol leaving group for non-metallocene olefin polymerization catalysts 有权非茂金属烯烃聚合催化剂的氟醇离去基团公开(公告)号：US07479529B2
公开(公告)日：2009-01-20
申请号：US11633197
申请日：2006-12-04
CPC分类号： C08F10/00 , C07F7/003 , C08F210/16 , C08F210/14 , C08F4/64148
摘要： A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 14 to Group 16 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.
摘要翻译： 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由式alphamatabgammagMXn表示，其中M是金属; X是卤代芳氧基; β和γ是各自包含至少一个第14族至第16族原子的基团; α是与β和γ各自形成化学键的连接部分; a，b，g和n分别为1〜4的整数。
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10.发明申请HYDROSILYLATION INHIBITOR, HYDROSILYLATION CATALYST COMPOSITION, AND CURABLE COMPOSITION 审中-公开氢化抑制剂，氢化催化剂组合物和可固化组合物公开(公告)号：US20080227938A1
公开(公告)日：2008-09-18
申请号：US12045238
申请日：2008-03-10
申请人： Shinji KIMURA , Hiroyasu Hara , Masayuki Ikeno
发明人： Shinji KIMURA , Hiroyasu Hara , Masayuki Ikeno
CPC分类号： C08L83/04 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/80 , C08K5/0091 , C08L83/00 , C08L2666/52
摘要： A hydrosilylation inhibitor comprising a reaction product of (1) a titanium compound having an alkoxy group in its ligand, and (2) an organosilicon compound having at least one hydrogen atom bonded to silicon atom per molecule is provided. This hydrosilylation inhibitor exhibits inhibitory activity for catalytic activity of a PGE (platinum group element)-bearing hydrosilylation catalyst in an oxygen atmosphere of up to 100 ppm and/or a moisture atmosphere of up to 100 ppm. By using the present invention, catalytic function of the hydrosilylation catalyst is reliably inhibited in the absence of oxygen and moisture while the same catalytic function is easily provided in the presence of the oxygen or the moisture.
摘要翻译： 提供了一种氢化硅烷化抑制剂，其包含（1）在其配体中具有烷氧基的钛化合物和（2）每分子具有至少一个与硅原子键合的氢原子的有机硅化合物的反应产物。 该氢化硅烷化抑制剂在高达100ppm的氧气氛和/或高达100ppm的湿气气氛中表现出对PGE（铂族元素）的氢化硅烷化催化剂的催化活性的抑制活性。 通过使用本发明，在没有氧气和水分的情况下，可靠地抑制氢化硅烷化催化剂的催化功能，而在氧气或水分的存在下容易提供相同的催化功能。
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