发明授权
- 专利标题: Polar grafted polyolefins, methods for their manufacture, and lubricating oil compositions containing them
- 专利标题(中): 极性接枝聚烯烃,其制造方法和含有它们的润滑油组合物
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申请号: US646454申请日: 1996-05-07
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公开(公告)号: US5814586A公开(公告)日: 1998-09-29
- 发明人: Frederick J. Boden , Richard P. Sauer , Irwin L. Goldblatt , Michael E. McHenry
- 申请人: Frederick J. Boden , Richard P. Sauer , Irwin L. Goldblatt , Michael E. McHenry
- 申请人地址: GB2 Swindon
- 专利权人: Castrol Limited
- 当前专利权人: Castrol Limited
- 当前专利权人地址: GB2 Swindon
- 主分类号: C08F255/00
- IPC分类号: C08F255/00 ; C08F255/02 ; C08F255/04 ; C08F255/06 ; C08F255/08 ; C08F257/02 ; C08F279/02 ; C08L51/00 ; C08L51/06 ; C10M143/00 ; C10M149/06 ; C10M149/10 ; C10M151/02 ; C10M157/04 ; C10M167/00 ; C10N30/04 ; C10N40/25
摘要:
A grafted polyolefin containing at least about 13 moles of N-vinylimidazole or other ethylenically-unsaturated nitrogen-containing and/or oxygen-containing monomers per mole of a grafted polyolefin backbone is disclosed. The graft polyolefin has a weight average molecular weight of from about 20,000 to about 500,000 and a polydispersity of less than about 10. The grafted polyolefin can alternatively be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant-viscosity index improver. N-vinylimidazole or other ethylenically unsaturated nitrogen-containing and/or oxygen-containingmonomers and a graftable polyolefin are reacted with enough of an initiator to graft at least about 13 moles of the monomer to each mole of the polyolefin. The initiator and/or monomer is added to the other ingredients, maintained at the reaction temperature, over a period of time. The reaction temperature is maintained at a level high enough to give acceptable reaction times. In one embodiment, the N-vinylimidazole and the initiator are each added at a uniform, relatively slow rate during the reaction.
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