发明授权
- 专利标题: Catalyst which can be used for the preparation of olefins during polymerization
- 专利标题(中): 可用于在聚合过程中制备烯烃的催化剂
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申请号: US464459申请日: 1995-06-05
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公开(公告)号: US6051522A公开(公告)日: 2000-04-18
- 发明人: Jurgen Rohrmann , Frank Kuber
- 申请人: Jurgen Rohrmann , Frank Kuber
- 申请人地址: DEX
- 专利权人: Targor GmbH
- 当前专利权人: Targor GmbH
- 当前专利权人地址: DEX
- 优先权: DEX4135594 19911130
- 主分类号: C07B61/00
- IPC分类号: C07B61/00 ; C07C1/207 ; C07C1/24 ; C07C13/465 ; C07C13/547 ; C07C13/66 ; C07C17/00 ; C07C17/361 ; C07C22/08 ; C07C23/34 ; C07C25/22 ; C07C41/30 ; C07C43/188 ; C07C43/192 ; C07C43/20 ; C07C43/215 ; C07C43/225 ; C07C45/46 ; C07C45/67 ; C07C49/665 ; C07C49/67 ; C07C49/675 ; C07F7/08 ; C07F9/00 ; C07F17/00 ; C07F19/00 ; C08F4/42 ; C08F4/602 ; C08F4/639 ; C08F4/6392 ; C08F4/64 ; C08F4/655 ; C08F4/659 ; C08F4/76 ; C08F10/00 ; C08F110/06 ; B01J31/00 ; B01J37/00 ; C08F4/02 ; C08F4/60
摘要:
A catalyst containing the combination which comprises:(a) an aluminoxane, a compound of the formula R.sub.x NH.sub.4-x, BR'.sub.4, R.sub.x PH.sub.4-x, BR'.sub.4, R.sub.3 CBR'.sub.4 or BR'.sub.3, or a mixture thereof wherein X is an integer from 1 to 4 and the radicals R are identical or different and are a C.sub.1 -C.sub.10 -alkyl or a C.sub.6 -C.sub.18 -aryl or 2 radicals R together with the atom joining them form a ring, and the radicals R' are identical or different and are a C.sub.6 -C.sub.18 -aryl which optionally are substituted by alkyl, haloalkyl or fluorine, and(b) a metallocene of the formula VI ##STR1## in which M.sup.1 is titanium, zirconium, hafnium, vanadium, niobium or tantalum,R.sup.1 is (C.sub.3 -C.sub.20)alkyl, (C.sub.6 -C.sub.14)aryl, (C.sub.4 -C.sub.10)alkoxy, (C.sub.2 -C.sub.10)alkenyl, (C.sub.7 -C.sub.20)arylalkyl, (C.sub.7 -C.sub.20)alkylaryl, (C.sub.6 -C.sub.10)aryloxy, (C.sub.1 -C.sub.10)fluoroalkyl, (C.sub.6 -C.sub.10)halogenoaryl, (C.sub.2 -C.sub.10)alkynyl; a radical --SiR.sup.6.sub.3, in which R.sup.6 is (C.sub.1 -C.sub.10)alkyl; a halogen atom; or an aromatic radical having 5 or 6 ring members in the ring, at lease one of which is a heteroatom,R.sup.2, R.sup.3 and R.sup.4 are identical or different and are hydrogen; (C.sub.1 -C.sub.20)alkyl, (C.sub.6 -C.sub.14)aryl, (C.sub.1 -C.sub.10)alkoxy, (C.sub.2 -C.sub.10)alkenyl, (C.sub.7 -C.sub.20)arylalkyl, (C.sub.7 -C.sub.20)alkylaryl, (C.sub.6 -C.sub.10)aryloxy, (C.sub.1 -C.sub.10)fluoroalkyl, (C.sub.6 -C.sub.10)halogenoaryl, (C.sub.2 -C.sub.10)alkynyl; a radical --SiR.sup.6.sub.3, in which R.sup.6 is (C.sub.1 -C.sub.10)alkyl, a halogen atom, or a heteroaromatic radical which has 5 or 6 ring members and can contain one or more heteroatoms, or adjacent radicals R.sup.1 -R.sup.4 ; with the atoms joining them, form one or more rings,R.sup.5 is hydrogen,R.sup.7 is a radical ##STR2## in which M.sup.2 is carbon, silicon, germanium or tin.
公开/授权文献
- US5058622A Valve lock assembly 公开/授权日:1991-10-22
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