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    Catalyst which can be used for the preparation of olefins during polymerization
    1.
    发明授权
    Catalyst which can be used for the preparation of olefins during polymerization 失效
    可用于在聚合过程中制备烯烃的催化剂

    公开(公告)号：US6051522A

    公开(公告)日：2000-04-18

    申请号：US464459

    申请日：1995-06-05

    申请人： Jurgen Rohrmann ,  Frank Kuber

    发明人： Jurgen Rohrmann ,  Frank Kuber

    IPC分类号： C07B61/00 ,  C07C1/207 ,  C07C1/24 ,  C07C13/465 ,  C07C13/547 ,  C07C13/66 ,  C07C17/00 ,  C07C17/361 ,  C07C22/08 ,  C07C23/34 ,  C07C25/22 ,  C07C41/30 ,  C07C43/188 ,  C07C43/192 ,  C07C43/20 ,  C07C43/215 ,  C07C43/225 ,  C07C45/46 ,  C07C45/67 ,  C07C49/665 ,  C07C49/67 ,  C07C49/675 ,  C07F7/08 ,  C07F9/00 ,  C07F17/00 ,  C07F19/00 ,  C08F4/42 ,  C08F4/602 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/655 ,  C08F4/659 ,  C08F4/76 ,  C08F10/00 ,  C08F110/06 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

    CPC分类号： C08F10/00 ,  C07C13/465 ,  C07C13/547 ,  C07C45/46 ,  C07C45/67 ,  C07C49/665 ,  C07C49/67 ,  C07C49/675 ,  C07F17/00 ,  C07F7/0809 ,  C07C2102/08 ,  C07C2103/20 ,  C08F110/06 ,  C08F4/63912 ,  C08F4/63927 ,  C08F4/65912 ,  Y10S526/943

    摘要： A catalyst containing the combination which comprises:(a) an aluminoxane, a compound of the formula R.sub.x NH.sub.4-x, BR'.sub.4, R.sub.x PH.sub.4-x, BR'.sub.4, R.sub.3 CBR'.sub.4 or BR'.sub.3, or a mixture thereof wherein X is an integer from 1 to 4 and the radicals R are identical or different and are a C.sub.1 -C.sub.10 -alkyl or a C.sub.6 -C.sub.18 -aryl or 2 radicals R together with the atom joining them form a ring, and the radicals R' are identical or different and are a C.sub.6 -C.sub.18 -aryl which optionally are substituted by alkyl, haloalkyl or fluorine, and(b) a metallocene of the formula VI ##STR1## in which M.sup.1 is titanium, zirconium, hafnium, vanadium, niobium or tantalum,R.sup.1 is (C.sub.3 -C.sub.20)alkyl, (C.sub.6 -C.sub.14)aryl, (C.sub.4 -C.sub.10)alkoxy, (C.sub.2 -C.sub.10)alkenyl, (C.sub.7 -C.sub.20)arylalkyl, (C.sub.7 -C.sub.20)alkylaryl, (C.sub.6 -C.sub.10)aryloxy, (C.sub.1 -C.sub.10)fluoroalkyl, (C.sub.6 -C.sub.10)halogenoaryl, (C.sub.2 -C.sub.10)alkynyl; a radical --SiR.sup.6.sub.3, in which R.sup.6 is (C.sub.1 -C.sub.10)alkyl; a halogen atom; or an aromatic radical having 5 or 6 ring members in the ring, at lease one of which is a heteroatom,R.sup.2, R.sup.3 and R.sup.4 are identical or different and are hydrogen; (C.sub.1 -C.sub.20)alkyl, (C.sub.6 -C.sub.14)aryl, (C.sub.1 -C.sub.10)alkoxy, (C.sub.2 -C.sub.10)alkenyl, (C.sub.7 -C.sub.20)arylalkyl, (C.sub.7 -C.sub.20)alkylaryl, (C.sub.6 -C.sub.10)aryloxy, (C.sub.1 -C.sub.10)fluoroalkyl, (C.sub.6 -C.sub.10)halogenoaryl, (C.sub.2 -C.sub.10)alkynyl; a radical --SiR.sup.6.sub.3, in which R.sup.6 is (C.sub.1 -C.sub.10)alkyl, a halogen atom, or a heteroaromatic radical which has 5 or 6 ring members and can contain one or more heteroatoms, or adjacent radicals R.sup.1 -R.sup.4 ; with the atoms joining them, form one or more rings,R.sup.5 is hydrogen,R.sup.7 is a radical ##STR2## in which M.sup.2 is carbon, silicon, germanium or tin.

    摘要翻译： 含有该组合的催化剂包括：（a）铝氧烷，式RxNH4-x，BR'4，RxPH4-x，BR'4，R3CBR'4或BR'3的化合物或其混合物，其中X为 1〜4的整数，基团R相同或不同，为C1-C10-烷基或C6-C18-芳基或2个基团R与连接的原子一起形成环，基团R'相同 或不同的并且是任选被烷基，卤代烷基或氟取代的C 6 -C 18 - 芳基，和（b）式VI的茂金属，其中M 1是钛，锆，铪，钒，铌或钽，R 1是（ （C 1 -C 10）烷基，（C 6 -C 10）芳基，（C 1 -C 10）芳氧基，（C 1 -C 10） -C 10）氟代烷基，（C 6 -C 10）卤代芳基，（C 2 -C 10）炔基; 基团-SiR 63，其中R 6是（C 1 -C 10）烷基; 卤素原子; 或在环中具有5或6个环成员的芳族基团，其中至少一个为杂原子，R 2，R 3和R 4相同或不同，为氢; （C 1 -C 10）烷基，（C 6 -C 10）芳基，（C 1 -C 10）芳氧基，（C 1 -C 10） C1-C10）氟烷基，（C6-C10）卤代芳基，（C2-C10）炔基; 基团-SiR 63，其中R 6是（C 1 -C 10）烷基，卤素原子或具有5或6个环成员并且可以含有一个或多个杂原子或相邻基团R 1 -R 4的杂芳族基团; 原子连接它们，形成一个或多个环，R 5是氢，R 7是其中M 2是碳，硅，锗或锡的基团。

    Process for the preparation of polyolefins
    7.
    发明授权
    Process for the preparation of polyolefins 失效
    制备聚烯烃的方法

    公开(公告)号：US5672668A

    公开(公告)日：1997-09-30

    申请号：US107187

    申请日：1993-08-16

    申请人： Andreas Winter ,  Martin Antberg ,  Bernd Bachmann ,  Volker Dolle ,  Frank Kuber ,  Jurgen Rohrmann ,  Walter Spaleck

    发明人： Andreas Winter ,  Martin Antberg ,  Bernd Bachmann ,  Volker Dolle ,  Frank Kuber ,  Jurgen Rohrmann ,  Walter Spaleck

    IPC分类号： C07F17/00 ,  C08F4/44 ,  C08F4/60 ,  C08F4/602 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F10/00 ,  C08F110/06 ,  C08F297/08

    CPC分类号： C08F297/083 ,  C07F17/00 ,  C08F10/00 ,  C08F110/06 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/63927 ,  Y10S526/943

    摘要： A process for the preparation of an olefin polymer by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b, in which R.sup.a and R.sup.b are identical or different and are a hydrogen atom or a hydrocarbon radical having 1 to 14 carbon atoms, or R.sup.a and R.sup.b, together with the atoms connecting them, can form a ring, at a temperature of from -60.degree. to 200.degree. C., at a pressure of from 0.5 to 100 bar, in solution, in suspension or in the gas phase, in the presence of a catalyst formed from a metallocene in the meso-form or a meso:rac mixture, with meso:rac>1:99, as transition-metal compound and a cocatalyst, wherein the metallocene is a compound of the formula I, ##STR1## in which M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are identical or different and are methyl or chlorine, R.sup.3 and R.sup.6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R.sup.4 and R.sup.5 are hydrogen or as defined for R.sup.3 and R.sup.6, or R.sup.4 forms an aliphatic or aromatic ring with R.sup.6, or adjacent radicals R.sup.4 form a ring of this type, and R.sup.7 is a ##STR2## radical, and m plus n is zero or 1.

    摘要翻译： 通过聚合或共聚式Ra-CH = CH-Rb的烯烃制备烯烃聚合物的方法，其中Ra和Rb相同或不同，并且是氢原子或具有1至14碳原子的烃基 原子或R a和R b与连接它们的原子一起在-60至200℃的温度下，在0.5至100巴的压力下，在溶液中，悬浮液中或在 在由外消旋混合物中内消旋金属茂或内消旋混合物形成的催化剂的存在下，作为过渡金属化合物和助催化剂，其中金属茂是化合物 其中M1是Zr或Hf，R1和R2是相同或不同的，是甲基或氯的式I，其中R 3和R 6相同或不同，是甲基，异丙基，苯基，乙基或三氟甲基 ，R 4和R 5是氢或如对R 3和R 6所定义，或者R 4与R 6或相邻的镭形成脂族或芳族环 ls R4形成这种类型的环，而R7是a