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US6060579A Method for producing polybutylene terephthalate 失效
聚对苯二甲酸丁二醇酯的制造方法

Method for producing polybutylene terephthalate
Abstract:
A method for producing polybutylene terephthalate comprising continuously esterifying a dicarboxylic acid component consisting essentially of terephthalic acid with a diol component consisting essentially of 1,4-butanediol followed by polycondensing the resulting oligomer, wherein the esterification is effected in a molar ratio, P, of the diol component to the dicarboxylic acid component to fall between 1.1 and 1.6, in the presence of a combination of an organic titanium compound and an organic tin compound that satisfies the following requirement:amount of organic titanium compound (mol %).ltoreq.0.08.times.P-0.07where P=molar ratio of diol component to dicarboxylic acid component, and is followed by the polycondensation.
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