发明授权
US6063974A Silylated water vapor treated zinc or gallium promoted zeolite and use thereof for the conversion of non-aromatic hydrocarbons to olefins and aromatic hydrocarbons 失效
硅烷化水蒸汽处理的锌或镓促进沸石及其用于将非芳族烃转化为烯烃和芳族烃的沸石

Silylated water vapor treated zinc or gallium promoted zeolite and use
thereof for the conversion of non-aromatic hydrocarbons to olefins and
aromatic hydrocarbons
摘要:
A hydrocarbon conversion process in which the rate of coke formation is reduced without a significant sacrifice in light olefin and BTX yield by the use of a silylated, stabilized metal promoted zeolite catalyst. Another embodiment includes a novel silylated spinel/zeolite catalyst. Another embodiment includes a process for producing a zinc or gallium promoted zeolite in which the promoter is stabilized by a high temperature water vapor treatment in the presence of a metal oxide such as alumina and thereafter the stabilized catalyst precursor is calcined and silylated.
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