发明授权
US6069207A Anionically copolymerized living random (meth) acrylic copolymers and copolymers prepared therefrom 失效
阴离子共聚的活性无规(甲基)丙烯酸共聚物和由其制备的共聚物

Anionically copolymerized living random (meth) acrylic copolymers and
copolymers prepared therefrom
摘要:
Living random (meth)acrylic copolymers, facilely converted into random co(meth)acrylates and block copolymers thereof, comprise the anionic copolymerizates of at least one comonomer A with at least one comonomer B selected from among the (meth)acrylates and maleimides, at least one of the comonomers A and B comprising a (meth)acrylate, in the presence of (i) at least one alkali or alkaline earth metal, mono- or difunctional initiator and (ii) at least one ligand, for example a nonnitrogenous macrocyclic complexant, e.g., a crown ether, or an alkali metal alcoholate.
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