发明授权
- 专利标题: Vinyl-containing stereospecific polypropylene macromers
- 专利标题(中): 含乙烯基立体定向聚丙烯大分子单体
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申请号: US20101申请日: 1998-02-06
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公开(公告)号: US6117962A公开(公告)日: 2000-09-12
- 发明人: Weiqing Weng , Armen Dekmezian , Eric J. Markel , Avinash Gadkari , David L. Peters
- 申请人: Weiqing Weng , Armen Dekmezian , Eric J. Markel , Avinash Gadkari , David L. Peters
- 申请人地址: TX Houston
- 专利权人: Exxon Chemical Patents Inc.
- 当前专利权人: Exxon Chemical Patents Inc.
- 当前专利权人地址: TX Houston
- 主分类号: C08F290/04
- IPC分类号: C08F290/04 ; C08F4/645 ; C08F4/659 ; C08F4/6592 ; C08F110/06
摘要:
Stereospecific polypropylene macromers having a high percentage of vinyl terminal bonds and a method for preparing them are provided. The stereospecific polypropylene macromers have number average molecular weights (M.sub.n) of about 2,000 Daltons to about 50,000 Daltons, and the total number of vinyl groups per 1000 carbon atoms is greater than or equal to 7000.div.M.sub.n. The method for preparing the macromers involves:a) contacting, in solution, at a temperature from about 90.degree. C. to about 120.degree. C., two or more propylene monomers with a catalyst composition comprising a chiral, stereorigid transition metal catalyst compound; andb) recovering stereospecific polypropylene chains having number average molecular weights of about 2,000 Daltons to about 50,000 Daltons and significant vinyl unsaturation.
公开/授权文献
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