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公开(公告)号：US06197910B1
公开(公告)日：2001-03-06
申请号：US09020306
申请日：1998-02-06
IPC分类号： C08F11006
CPC分类号： C08L51/06 , C08F4/65912 , C08F10/00 , C08F10/06 , C08F110/06 , C08F255/00 , C08F255/02 , C08F290/042 , C08F297/08 , C08F297/083 , Y10S526/943 , C08F4/65927 , C08F2500/15 , C08F2500/03 , C08F2500/06 , C08F2500/09
摘要： A polyolefin composition is provided which consists essentially of isotactic polypropylene and, optionally, repeating units of one or more comonomers, wherein the total comonomer repeating unit content of the polyolefin composition is from 0 to 20 mole percent, and further, wherein the weight average branching index g′ for the lower molecular weight region of the polyolefin composition is less than 0.93. Additionally, a process is provided for producing a polyolefin composition comprising: a) contacting, in solution, at a temperature from about 90° C. to about 120° C., propylene monomers with a catalyst composition comprising a first chiral, stereorigid transition metal catalyst compound capable of producing isotactic polypropylene; b) copolymerizing the product of a) with propylene and, optionally, one or more copolymerizable monomers, in a polymerization reactor under suitable polypropylene polymerization conditions using a second chiral, stereorigid transition metal catalyst capable of producing isotactic polypropylene; and c) recovering a branched olefin polymer.
摘要翻译： 提供了聚烯烃组合物，其基本上由全同立构聚丙烯和任选的一种或多种共聚单体的重复单元组成，其中聚烯烃组合物的总共聚单体重复单元含量为0至20摩尔％，此外，其中重均分子量 聚烯烃组合物的较低分子量区域的指数g'小于0.93。 此外，提供了一种用于制备聚烯烃组合物的方法，其包括：a）在约90℃至约120℃的温度下在溶液中使丙烯单体与催化剂组合物接触，所述催化剂组合物包含第一手性立体刚性过渡金属 能够产生全同立构聚丙烯的催化剂化合物; b）在合适的聚丙烯聚合条件下，使用能够产生全同立构的第二手性立体刚性过渡金属催化剂，在聚合反应器中将a）的产物与丙烯和任选的一种或多种可共聚的单体共聚 聚丙烯; 和c）回收支链烯烃聚合物。
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公开(公告)号：US6117962A
公开(公告)日：2000-09-12
申请号：US20101
申请日：1998-02-06
IPC分类号： C08F290/04 , C08F4/645 , C08F4/659 , C08F4/6592 , C08F110/06
CPC分类号： C08F110/06 , C08F4/65908 , C08F4/65912
摘要： Stereospecific polypropylene macromers having a high percentage of vinyl terminal bonds and a method for preparing them are provided. The stereospecific polypropylene macromers have number average molecular weights (M.sub.n) of about 2,000 Daltons to about 50,000 Daltons, and the total number of vinyl groups per 1000 carbon atoms is greater than or equal to 7000.div.M.sub.n. The method for preparing the macromers involves:a) contacting, in solution, at a temperature from about 90.degree. C. to about 120.degree. C., two or more propylene monomers with a catalyst composition comprising a chiral, stereorigid transition metal catalyst compound; andb) recovering stereospecific polypropylene chains having number average molecular weights of about 2,000 Daltons to about 50,000 Daltons and significant vinyl unsaturation.
摘要翻译： 提供了具有高百分比乙烯基端键的立体特异性聚丙烯大分子单体及其制备方法。 立体有择性聚丙烯大分子单体的数均分子量（Mn）为约2,000道尔顿至约50,000道尔顿，每1000个碳原子的乙烯基总数大于或等于7000分子量Mn。 制备大分子单体的方法包括：a）在溶液中，在约90℃至约120℃的温度下接触两种或多种具有包含手性立体刚性过渡金属催化剂化合物的催化剂组合物的丙烯单体; 和b）回收数均分子量为约2,000道尔顿至约50,000道尔顿的立体有择聚丙烯链和显着的乙烯基不饱和度。
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公开(公告)号：US06750307B2
公开(公告)日：2004-06-15
申请号：US10295026
申请日：2002-11-14
IPC分类号： C08F21016
CPC分类号： C08L55/005 , C08F2/08 , C08F110/02 , C08F210/18 , C08F255/00 , C08F255/02 , C08F257/02 , C08F290/00 , C08F290/04 , C08F290/042 , C08F290/044 , C08F297/08 , C08F297/083 , C08L23/02 , C08L23/08 , C08L23/0815 , C08L51/06 , C08L55/00 , C08L2205/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/02 , C08F2500/03 , C08F2500/09 , C08F2500/12 , C08F210/08 , C08L2666/06
摘要： A polyolefin product is provided which comprises a branched olefin copolymer having an isotactic polypropylene backbone, polyethylene branches and, optionally, one or more comonomers. The total comonomer content of the branched olefin copolymer is from 0 to 20 mole percent. Also, the mass ratio of the isotactic polypropylene to the polyethylene ranges from 99.9:0.1 to 50:50. Additionally, a process is provided for preparing a branched olefin copolymer which comprises: a) copolymerizing ethylene, optionally with one or more copolymerizable monomers, in a polymerization reaction under conditions sufficient to form copolymer having greater than 40% chain end-group unsaturation; b) copolymerizing the product of a) with propylene and, optionally, one or more copolymerizable monomers, in a polymerization reactor under suitable polypropylene polymerization conditions using a chiral, stereorigid transition metal catalyst capable of producing isotactic polypropylene; and c) recovering a branched olefin copolymer.
摘要翻译： 提供了一种聚烯烃产品，其包含具有全同立构聚丙烯骨架的支链烯烃共聚物，聚乙烯分支和任选的一种或多种共聚单体。 支链烯烃共聚物的总共聚单体含量为0〜20摩尔％。 另外，全同立构聚丙烯与聚乙烯的质量比为99.9:0.1〜50:50。 另外，提供了一种制备支链烯烃共聚物的方法，其包括：a）在足以形成具有大于40％的链端基不饱和度的共聚物的条件下，在聚合反应中将乙烯任选地与一种或多种可共聚单体共聚; b ）使用可产生全同立构聚丙烯的手性立体刚性过渡金属催化剂，在合适的聚丙烯聚合条件下，在聚合反应器中将a）的产物与丙烯和任选的一种或多种可共聚单体共聚; 和c）回收支链烯烃共聚物。
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公开(公告)号：US06660809B1
公开(公告)日：2003-12-09
申请号：US09020307
申请日：1998-02-06
IPC分类号： C08F25500
CPC分类号： C08L55/005 , C08F2/08 , C08F110/02 , C08F210/18 , C08F255/00 , C08F255/02 , C08F257/02 , C08F290/00 , C08F290/04 , C08F290/042 , C08F290/044 , C08F297/08 , C08F297/083 , C08L23/02 , C08L23/08 , C08L23/0815 , C08L51/06 , C08L55/00 , C08L2205/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/02 , C08F2500/03 , C08F2500/09 , C08F2500/12 , C08F210/08 , C08L2666/06
摘要： A polyolefin product is provided which comprises a branched olefin copolymer having an isotactic polypropylene backbone, polyethylene branches and, optionally, one or more comonomers. The total comonomer content of the branched olefin copolymer is from 0 to 20 mole percent. Also, the mass ratio of the isotactic polypropylene to the polyethylene ranges from 99.9:0.1 to 50:50. Additionally, a process is provided for preparing a branched olefin copolymer which comprises: a) copolymerizing ethylene, optionally with one or more copolymerizable monomers, in a polymerization reaction under conditions sufficient to form copolymer having greater than 40% chain end-group unsaturation; b) copolymerizing the product of a) with propylene and, optionally, one or more copolymerizable monomers, in a polymerization reactor under suitable polypropylene polymerization conditions using a chiral, stereorigid transition metal catalyst capable of producing isotactic polypropylene; and c) recovering a branched olefin copolymer.
摘要翻译： 提供了一种聚烯烃产品，其包含具有全同立构聚丙烯骨架的支链烯烃共聚物，聚乙烯分支和任选的一种或多种共聚单体。 支链烯烃共聚物的总共聚单体含量为0〜20摩尔％。 另外，全同立构聚丙烯与聚乙烯的质量比为99.9:0.1〜50:50。 另外，提供了一种制备支链烯烃共聚物的方法，其包括：a）在足以形成具有大于40％的链端基不饱和度的共聚物的条件下，在聚合反应中将乙烯任选地与一种或多种可共聚单体共聚; b ）使用可产生全同立构聚丙烯的手性立体刚性过渡金属催化剂，在合适的聚丙烯聚合条件下，在聚合反应器中将a）的产物与丙烯和任选的一种或多种可共聚单体共聚; 和c）回收支链烯烃共聚物。
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公开(公告)号：US06774191B2
公开(公告)日：2004-08-10
申请号：US10640153
申请日：2003-08-13
IPC分类号： C08F25500
CPC分类号： C08L55/005 , C08F2/08 , C08F110/02 , C08F210/18 , C08F255/00 , C08F255/02 , C08F257/02 , C08F290/00 , C08F290/04 , C08F290/042 , C08F290/044 , C08F297/08 , C08F297/083 , C08L23/02 , C08L23/08 , C08L23/0815 , C08L51/06 , C08L55/00 , C08L2205/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/02 , C08F2500/03 , C08F2500/09 , C08F2500/12 , C08F210/08 , C08L2666/06
摘要： A polyolefin product is provided which comprises a branched olefin copolymer having an syndiotactic polypropylene backbone, polyethylene branches and, optionally, one or more comonomers. The total comonomer content of the branched olefin copolymer is from 0 to 20 mole percent. Also, the mass ratio of the syndiotactic polypropylene to the polyethylene ranges from 99.9:0.1 to 50:50. Additionally, a process is provided for preparing a branched olefin copolymer which comprises: a) copolymerizing ethylene, optionally with one or more copolymerizable monomers, in a polymerization reaction under conditions sufficient to form copolymer having greater than 40% chain end-group unsaturation; b) copolymerizing the product of a) with propylene and, optionally, one or more copolymerizable monomers, in a polymerization reactor under suitable polypropylene polymerization conditions using a chiral, stereorigid transition metal catalyst capable of producing syndiotactic polypropylene; and c) recovering a branched olefin copolymer.
摘要翻译： 提供了一种聚烯烃产品，其包含具有间同立构聚丙烯主链，聚乙烯分支和任选的一种或多种共聚单体的支链烯烃共聚物。 支链烯烃共聚物的总共聚单体含量为0〜20摩尔％。 另外，间同立构聚丙烯与聚乙烯的质量比为99.9:0.1〜50:50。 另外，提供了一种制备支链烯烃共聚物的方法，其包括：a）在足以形成具有大于40％的链端基不饱和度的共聚物的条件下，在聚合反应中将乙烯任选地与一种或多种可共聚单体共聚; b ）使用可产生间同立构聚丙烯的手性立体刚性过渡金属催化剂，在合适的聚丙烯聚合条件下，在聚合反应器中将a）的产物与丙烯和任选的一种或多种可共聚单体共聚; 和c）回收支链烯烃共聚物。
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6.发明申请公开(公告)号：US20050203252A1
公开(公告)日：2005-09-15
申请号：US11123904
申请日：2005-05-06
申请人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
发明人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
IPC分类号： C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L51/06 , C08L53/00 , C08L23/00
CPC分类号： C08L51/06 , C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L53/00 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/06 , C08L2666/02 , C08F210/16 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
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7.发明申请公开(公告)号：US20060004146A1
公开(公告)日：2006-01-05
申请号：US11213537
申请日：2005-08-26
申请人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
发明人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
IPC分类号： C08L23/00
CPC分类号： C08L51/06 , C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L53/00 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/06 , C08L2666/02 , C08F210/16 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
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8.发明申请Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers 有权全同立构聚丙烯和α-烯烃/丙烯共聚物的热塑性聚合物共混物公开(公告)号：US20050282964A1
公开(公告)日：2005-12-22
申请号：US11213508
申请日：2005-08-26
申请人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
发明人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
IPC分类号： C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L51/06 , C08L53/00 , C08L23/00
CPC分类号： C08L51/06 , C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L53/00 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/06 , C08L2666/02 , C08F210/16 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
摘要翻译： 包含全同立构聚丙烯组分和α-烯烃和丙烯共聚物组分的改进的热塑性聚合物共混组合物，所述共聚物包含可结晶的α-烯烃序列。 在优选的实施方案中，提供了改进的热塑性聚合物共混物，其包含约35％至约85％的全同立构聚丙烯和约30％至约70％的乙烯和丙烯共聚物，其中所述共聚物包含等度可结晶的丙烯序列，并且主要为丙烯 。 所得到的共混物表现出意想不到的相容特性，增加的拉伸强度和改进的工艺特性，例如单一熔点。
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9.发明申请公开(公告)号：US20060004145A1
公开(公告)日：2006-01-05
申请号：US11213531
申请日：2005-08-26
申请人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
发明人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
IPC分类号： C08L23/00
CPC分类号： C08L51/06 , C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L53/00 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/06 , C08L2666/02 , C08F210/16 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
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10.发明申请公开(公告)号：US20050137343A1
公开(公告)日：2005-06-23
申请号：US11058789
申请日：2005-02-16
申请人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
发明人： Sudhin Datta , Avinash Gadkari , Charles Cozewith
IPC分类号： C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L51/06 , C08L53/00 , C08L23/00
CPC分类号： C08L51/06 , C08F210/06 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L53/00 , C08L2205/02 , C08L2205/03 , C08L2314/02 , C08L2314/06 , C08L2666/24 , C08L2666/04 , C08L2666/06 , C08L2666/02 , C08F210/16 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
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