A method of forming a gate electrode with a titanium polycide which can prevent particle creation and abnormal oxidation of the gate electrode, is disclosed. In the present invention, a gate oxidation process is performed after implanting Si ions into the side wall or overall surface of the titanium silicide layer, thereby preventing abnormal oxidation of the titanium silicide during the gate oxidation process. Furthermore, a titanium silicide layer is deposited to a low mole ratio of Si/Ti, thereby minimizing particle creation.