Invention Grant
US06525234B1 Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds
有权
液相芳烃烷基化方法,包括用极性化合物原位催化剂再活化
- Patent Title: Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds
- Patent Title (中): 液相芳烃烷基化方法,包括用极性化合物原位催化剂再活化
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Application No.: US09717705Application Date: 2000-11-21
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Publication No.: US06525234B1Publication Date: 2003-02-25
- Inventor: Ajit B. Dandekar , Thomas Francis Degnan , John P. McWilliams , Chaya R. Venkat
- Applicant: Ajit B. Dandekar , Thomas Francis Degnan , John P. McWilliams , Chaya R. Venkat
- Main IPC: C07C268
- IPC: C07C268

Abstract:
A process for alkylating aromatics comprises: i) contacting a feed containing alkylatable aromatic, e.g., benzene, under liquid phase alkylating conditions with an alkylating agent, e.g., ethylene, in the presence of an alkylation catalyst comprising a porous crystalline material, e.g., MCM-22, to provide an alkylated aromatic product during which contacting said catalyst becomes at least partially deactivated by sorbing catalyst poisons present in said feed; ii) treating said at least partially deactivated catalyst in situ by contacting with at least one polar compound, e.g., water or acetic acid, having a dipole moment of at least 0.05 Debyes under conditions of temperature and pressure employed in said liquid phase alkylating conditions which are sufficient to at least partially desorb said catalyst poison from said catalyst; and iii) collecting said alkylated aromatic product.
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