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    Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds
    1.
    发明授权
    Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds 有权
    液相芳烃烷基化方法，包括用极性化合物原位催化剂再活化

    公开(公告)号：US06909026B2

    公开(公告)日：2005-06-21

    申请号：US10318882

    申请日：2002-12-13

    Applicant: Ajit B. Dandekar ,  Thomas Francis Degnan ,  John P. McWilliams ,  Chaya R. Venkat

    Inventor： Ajit B. Dandekar ,  Thomas Francis Degnan ,  John P. McWilliams ,  Chaya R. Venkat

    IPC: C07C2/66 ,  C07C2/68

    CPC classification number: C07C2/66 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073

    Abstract: The catalyst becomes at least partially deactivated by sorbing catalyst poisons present in the feed during a process for alkylating aromatics by contacting a feed containing benzene, toluene, xylenes, alkylbenzenes, naphthalene or substituted naphthalenes under liquid phase alkylating conditions with C2-C16 olefins in the presence of MCM-22, MCM-36, MCM-49, MCM-56, ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-48, ZSM-50, ZSM-4, ZSM-18, ZSM-20, Zeolite X, Zeolite Y, USY, mordenite or offretite to provide an alkylated aromatic product. The at least partially deactivated catalyst can be treated in situ by contacting with at least one polar compound having a dipole moment of at least 0.05 Debyes and selected from the group consisting of acetic acid, formic acid, water, and carbon monoxide, under conditions of temperature and pressure employed in the liquid phase alkylating conditions which are sufficient to at least partially desorb the catalyst poison from the catalyst.

    Abstract translation: 在芳族化合物的烷基化方法中，通过在液相烷基化条件下将含有苯，甲苯，二甲苯，烷基苯，萘或取代萘的进料与C 2 H 2化合物接触，使催化剂至少部分失活， 在MCM-22，MCM-36，MCM-49，MCM-56，ZSM-5，ZSM-11，ZSM-12，ZSM-23等的存在下， ZSM-35，ZSM-48，ZSM-50，ZSM-4，ZSM-18，ZSM-20，沸石X，沸石Y，USY，丝光沸石或黑斑，提供烷基化芳族产物。 所述至少部分失活的催化剂可以通过与至少一种偶极矩至少为0.05德拜的极性化合物接触而原位处理，并选自乙酸，甲酸，水和一氧化碳，条件是 在液相烷基化条件下使用的足以使催化剂毒物至少部分解吸的催化剂的温度和压力。

    Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
    2.
    发明授权
    Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation 失效
    使用液相烷基化和气相烷基转移制备乙苯的连续方法

    公开(公告)号：US5600048A

    公开(公告)日：1997-02-04

    申请号：US364145

    申请日：1994-12-27

    Applicant: Jane C. Cheng ,  C. Morris Smith ,  Chaya R. Venkat ,  Dennis E. Walsh

    Inventor： Jane C. Cheng ,  C. Morris Smith ,  Chaya R. Venkat ,  Dennis E. Walsh

    IPC: B01J29/70 ,  C07C2/66 ,  C07C6/12 ,  C07C15/073

    CPC classification number: C07C15/073 ,  C07C6/126 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/582

    Abstract: There is provided a process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation. The liquid phase alkylation reaction may be catalyzed by an acidic solid oxide, such as MCM-22, MCM-49 and MCM-56. The vapor phase transalkylation may be catalyzed by a medium-pore size zeolite such as ZSM-5. The process may be run continuously with the continuous introduction of fresh benzene feed containing at least 500 ppm of nonbenzene hydrocarbon impurities. The combined ethylbenzene product of these alkylation and transalkylation reactions has very low levels of impurities including xylene, hydrocarbons having 7 or less carbon atoms and hydrocarbons having 9 or more carbon atoms.

    Abstract translation: 提供了使用液相烷基化和气相烷基转移制备乙苯的方法。 液相烷基化反应可以由酸性固体氧化物如MCM-22，MCM-49和MCM-56催化。 气相烷基转移可以通过中等孔径的沸石催化，例如ZSM-5。 该方法可以连续引入含有至少500ppm非苯烃杂质的新鲜苯进料而连续进行。 这些烷基化和烷基转移反应的组合乙苯产物具有非常低的杂质含量，包括二甲苯，具有7个或更少碳原子的烃和具有9个或更多个碳原子的烃。

    Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds
    3.
    发明授权
    Process for liquid phase aromatics alkylation comprising in-situ catalyst reactivation with polar compounds 有权
    液相芳烃烷基化方法，包括用极性化合物原位催化剂再活化

    公开(公告)号：US06525234B1

    公开(公告)日：2003-02-25

    申请号：US09717705

    申请日：2000-11-21

    Applicant: Ajit B. Dandekar ,  Thomas Francis Degnan ,  John P. McWilliams ,  Chaya R. Venkat

    Inventor： Ajit B. Dandekar ,  Thomas Francis Degnan ,  John P. McWilliams ,  Chaya R. Venkat

    IPC: C07C268

    CPC classification number: C07C2/66 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073

    Abstract: A process for alkylating aromatics comprises: i) contacting a feed containing alkylatable aromatic, e.g., benzene, under liquid phase alkylating conditions with an alkylating agent, e.g., ethylene, in the presence of an alkylation catalyst comprising a porous crystalline material, e.g., MCM-22, to provide an alkylated aromatic product during which contacting said catalyst becomes at least partially deactivated by sorbing catalyst poisons present in said feed; ii) treating said at least partially deactivated catalyst in situ by contacting with at least one polar compound, e.g., water or acetic acid, having a dipole moment of at least 0.05 Debyes under conditions of temperature and pressure employed in said liquid phase alkylating conditions which are sufficient to at least partially desorb said catalyst poison from said catalyst; and iii) collecting said alkylated aromatic product.

    Abstract translation: 烷基化芳族化合物的方法包括：i）在液相烷基化条件下，在包含多孔结晶材料的烷基化催化剂（例如MCM）的存在下，使含有可烷基化芳族化合物（例如苯）的进料与烷基化试剂例如乙烯接触 -22，以提供烷基化芳族产物，其中通过吸附所述进料中存在的催化剂毒物使所述催化剂接触至少部分失活; ii）通过与至少一种极性化合物接触来处理所述至少部分失活的催化剂，例如， 水或乙酸，其在所述液相烷基化条件下使用的温度和压力条件下的偶极矩至少为0.05德拜，其足以使所述催化剂毒物至少部分地解吸所述催化剂毒物; 和ii）收集所述烷基化芳族产物。

    Pyridine/picoline production process
    10.
    发明授权
    Pyridine/picoline production process 失效
    吡啶/甲基吡啶生产工艺

    公开(公告)号：US5969143A

    公开(公告)日：1999-10-19

    申请号：US2363

    申请日：1997-12-31

    Applicant: Arthur Chester ,  Scott Han ,  Dominick N. Mazzone ,  Chaya R. Venkat

    Inventor： Arthur Chester ,  Scott Han ,  Dominick N. Mazzone ,  Chaya R. Venkat

    IPC: C07D213/06 ,  C07B61/00 ,  C07C211/00 ,  C07D213/08 ,  C07D213/10 ,  C07D213/14 ,  C07G213/09

    CPC classification number: C07C211/00 ,  C07D213/06 ,  C07D213/08 ,  C07D213/10 ,  C07D213/14 ,  C07B61/00

    Abstract: There is provided a high efficiency base synthesis process for shape selective production of pyridine and picoline products from ammonia and C.sub.1-5 carbonyl compounds. The process includes reacting ammonia and at least one C.sub.1-5 carbonyl reactant under suitable reaction conditions of temperature, pressure, and space velocity in the presence of a catalyst comprising a molecular sieve to produce a primary product comprising pyridine or picoline products and polyalkylpyridines or other higher molecular weight aromatic species, separating and collecting the pyridine or picoline products from the polyalkylpyridines or other higher molecular weight aromatic species, and circulating the polyalkylpyridines or other higher molecular weight aromatic species to the same or another catalyst under conversion conditions to yield additional pyridine or picoline products with substantially reduced amounts of polyalkylpyridines or other higher molecular weight aromatic species.

    Abstract translation: 提供了一种从氨和C 1-5羰基化合物形成选择性生产吡啶和甲基吡啶产物的高效碱基合成方法。 该方法包括在包含分子筛的催化剂存在下，在温度，压力和空间速度的合适反应条件下使氨和至少一种C 1-5羰基反应物反应，以产生包含吡啶或甲基吡啶产物和聚烷基吡啶或其它 较高分子量的芳族物质，从聚烷基吡啶或其它较高分子量的芳族物质中分离和收集吡啶或甲基吡啶产物，并将多烷基吡啶或其它较高分子量的芳族物质在转化条件下循环至相同或另一种催化剂，以产生额外的吡啶或 具有大量减少量的聚烷基吡啶或其它较高分子量芳族物质的甲基吡啶产物。

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