发明授权
US06653407B2 Process for preparing star shaped microgels from macromonomers with terminal ethylenic unsaturation 有权
从具有末端烯属不饱和键的大分子单体制备星形微凝胶的方法

Process for preparing star shaped microgels from macromonomers with terminal ethylenic unsaturation
摘要:
The present invention is directed to a process for forming star shaped microgels which include a core of crosslinked polymer and multiplicity of substantially linear polymeric arms of macromonomers attached to the core. The process includes polymerizing monoethylenically unsaturated monomers in the presence of a chain transfer agent to form macromonomers each having a terminal polymerizable ethylenically unsaturated group and then polymerizing, in presence of the macromonomers, the monoethylenically unsaturated monomers and multi-olefinic crosslinking monomers. The microgels of the present invention can be used as rheology control agents in waterborne and solvent-borne coatings and in adhesives and cosmetics.
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