发明授权
US06696616B2 Process for co-production of metaxylene and paraxylene 有权
共生产间二甲苯和对二甲苯的方法

  • 专利标题: Process for co-production of metaxylene and paraxylene
  • 专利标题(中): 共生产间二甲苯和对二甲苯的方法
  • 申请号: US09842262
    申请日: 2001-04-26
  • 公开(公告)号: US06696616B2
    公开(公告)日: 2004-02-24
  • 发明人: Didier PavoneGerard Hotier
  • 申请人: Didier PavoneGerard Hotier
  • 优先权: FR0005424 20000427
  • 主分类号: C07C712
  • IPC分类号: C07C712
Process for co-production of metaxylene and paraxylene
摘要:
For co-production of metaxylene and paraxylene from a hydrocarbon feedstock in a simulated moving bed in a chromatographic column (1) that contains a number of beds 1, 2,3, 4 . . . of an adsorbent, interconnected in a loop, the column comprises an injection of the feedstock, a draw-off (14) of a first raffinate, a draw-off (17) of a second raffinate that comprises metaxylene, an injection of desorbent and a draw-off of an extract that delivers paraxylene. The injection positions and the draw-off position of the extract are offset periodically by one bed in the direction of flow of the main flux that circulates in the column. First raffinate (14) that comprises desorbent, orthoxylene, metaxylene and ethylbenzene is drawn off continuously or intermittently, and second raffinate (17) R2 that comprises orthoxylene and metaxylene is drawn off intermittently. The second raffinate is distilled in such a way as to recover orthoxylene and metaxylene separately with at least 99% purity and with an improved yield. The resultant xylenes are suitable for the production of isophthalic acid and terephthalic acid
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