Invention Grant
US06831032B2 Ziegler-Natta catalyst and methods of making and using same 失效
齐格勒 - 纳塔催化剂及其制备和使用方法

  • Patent Title: Ziegler-Natta catalyst and methods of making and using same
  • Patent Title (中): 齐格勒 - 纳塔催化剂及其制备和使用方法
  • Application No.: US10223561
    Application Date: 2002-08-19
  • Publication No.: US06831032B2
    Publication Date: 2004-12-14
  • Inventor: Wolf Spaether
  • Applicant: Wolf Spaether
  • Main IPC: B01J3100
  • IPC: B01J3100
Ziegler-Natta catalyst and methods of making and using same
Abstract:
A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining a porous particulate support with a magnesium source in a hydrocarbon solvent to form a mixture, the magnesium source including a hydrocarbon soluble organomagnesium compound and a hydrocarbon insoluble anhydrous inorganic magnesium-halogen compound. The organomagnesium compound is halogenated and the mixture is reacted with a titanium compound or vanadium compound to form the solid catalyst component. The solid catalyst component is then recovered and combined with an organoaluminum cocatalyst to form a Ziegler-Natta catalyst which is advantageously used for the polymerization of olefins, particularly alk-1-enes such as ethylene, propylene, 1-butene, and the like. The catalyst can optionally include internal and external electron donors.
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