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    Method of making a ziegler-natta catalyst
    3.
    发明授权
    Method of making a ziegler-natta catalyst 有权
    制备齐格勒 - 纳塔催化剂的方法

    公开(公告)号：US07071137B2

    公开(公告)日：2006-07-04

    申请号：US10925596

    申请日：2004-08-25

    申请人： Douglas D. Klendworth ,  Frank Wolf Spaether

    发明人： Douglas D. Klendworth ,  Frank Wolf Spaether

    IPC分类号： B01J37/00

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/6543 ,  C08F4/022 ,  C08F4/025 ,  C08F4/6494

    摘要： A method for making a Ziegler-Natta catalyst support includes the steps of contacting a fumed silica with a surface modifying agent such as a compound having the formula RMgX MgR′R″ wherein R, R′ and R″ are each individually a moiety selected from an alkyl group, cycloalkyl, aryl or alkaryl group, and X is a halogen selected from the group consisting of chlorine, bromine and iodine, to provide a pretreated silica seeding agent. The pretreated silica seeding agent is then dispersed in a non-aqueous liquid magnesium halide/alkanol complex, and the magnesium halide is crystallized onto the silica particles to form catalyst support particles especially suitable for Ziegler-Natta catalysts.

    摘要翻译： 制备齐格勒 - 纳塔催化剂载体的方法包括使热解二氧化硅与表面改性剂如具有式RMgX MgR'R“的化合物接触的步骤，其中R，R'和R”各自为一部分 选自烷基，环烷基，芳基或烷芳基，X是选自氯，溴和碘的卤素，以提供预处理的二氧化硅接种剂。 然后将预处理的二氧化硅接种剂分散在非水性液体卤化镁/烷醇络合物中，并将卤化镁结晶到二氧化硅颗粒上以形成特别适合齐格勒 - 纳塔催化剂的催化剂载体颗粒。

    Catalyst systems of the Ziegler-Natta type
    4.
    发明授权
    Catalyst systems of the Ziegler-Natta type 失效
    齐格勒 - 纳塔型催化剂系统

    公开(公告)号：US06524995B2

    公开(公告)日：2003-02-25

    申请号：US09750715

    申请日：2001-01-02

    申请人： Wolf Spaether ,  Stephan Hüffer ,  John Lynch ,  Wolfgang Bidell ,  Joachim Rösch ,  Günther Schweier ,  Roland Hingmann ,  Alexandre Segul ,  Rainer Hemmerich ,  Ingo Treffkorn

    发明人： Wolf Spaether ,  Stephan Hüffer ,  John Lynch ,  Wolfgang Bidell ,  Joachim Rösch ,  Günther Schweier ,  Roland Hingmann ,  Alexandre Segul ,  Rainer Hemmerich ,  Ingo Treffkorn

    IPC分类号： B01J2302

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/025 ,  C08F4/6546 ,  C08F2500/12 ,  C08F2500/24

    摘要： Catalyst systems of the Ziegler-Natta type comprise as active constituents a) a solid component comprising a compound of titanium or vanadium, a compound of magnesium, a particulate inorganic oxide as support and an internal electron donor compound, and as cocatalyst b) an aluminum compound and c) if desired, a further, external electron donor compound, wherein the particulate, inorganic oxide used has a specific surface area of from 350 to 1000 m2/g and a mean particle diameter {overscore (D)} in the range from 5 to 60 &mgr;m and comprises particles which are composed of primary particles having a mean particle diameter {overscore (d)} in the range from 1 to 10 &mgr;m and contain voids or channels between the primary particles, where the macroscopic proportion of voids or channels having a diameter of greater than 1 &mgr;m in the particles of the inorganic oxides is in the range from 5 to 30% by volume and the molar ratio of the compound of magnesium to the particulate, inorganic oxide is from 0.5:1 to 2.0:1.

    摘要翻译： 齐格勒 - 纳塔型的催化剂体系包括作为活性成分的a）包含钛或钒的化合物的固体组分，镁的化合物，作为载体的颗粒状无机氧化物和内部电子给体化合物，以及作为助催化剂）铝化合物和 ），其中所用的颗粒状无机氧化物的比表面积为350〜1000m2 / g，平均粒径（超芯（D在5〜60μm的范围内）和 包含由平均粒径（超芯（d在1-10μm范围内）并且在初级颗粒之间含有空隙或通道的初级颗粒组成的颗粒，其中空隙或通道的宏观比例具有大于1的直径 无机氧化物颗粒中的母体在5至30体积％的范围内，镁与颗粒的无机氧化物的摩尔比为0.5:1至 2.0：1。

    Ziegler-natta catalyst, preparation, and use for the polymerization of alkenes
    5.
    发明授权
    Ziegler-natta catalyst, preparation, and use for the polymerization of alkenes 有权
    齐格勒 - 纳塔催化剂，制备和用于烯烃聚合的用途

    公开(公告)号：US07893175B2

    公开(公告)日：2011-02-22

    申请号：US12001729

    申请日：2007-12-12

    申请人： Frank Wolf Spaether ,  David Andrew Presken

    发明人： Frank Wolf Spaether ,  David Andrew Presken

    IPC分类号： C08F4/42

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/025 ,  C08F4/6546 ,  C08F4/651 ,  C08F2500/12

    摘要： A method for making a solid catalytic component for a Ziegler-Natta catalyst includes contacting a particulate porous support with a solution of a hydrocarbon soluble organomagnesium precursor compound in a hydrocarbon solvent; and reacting said hydrocarbon soluble organo-magnesium precursor compound with an amount of aliphatic or aromatic alcohol, said amount being within an acceptable range of a molar equivalent of aliphatic or aromatic alcohol calculated according to formula (I): Equ Alkanol = 2 · [ ( mmole ⁢ ⁢ MgR / g ⁢ ⁢ support ) - 2.1 - 0.55 · wt ⁢ ⁢ % ⁢ ⁢ ( H 2 ⁢ O ) / support ] [ mmole ⁢ ⁢ MgR / g ⁢ ⁢ support ] ( I ) wherein EquAlkanol=molar equivalents of aliphatic or aromatic alkanol relative to the molar amount of magnesium-organic precursor, (mmole MgR/g support)=mmoles of magnesium-organic precursor per gram of particulate solid support, wt % (H2O)/support=weight percent of physically adsorbed water on the solid support, and said magnesium organic precursor compound being converted to a magnesium-oxygen compound.

    摘要翻译： 用于制备齐格勒 - 纳塔催化剂的固体催化组分的方法包括使颗粒状多孔载体与烃溶性有机镁前体化合物在烃溶剂中的溶液接触; 并使所述烃溶性有机镁前体化合物与一定量的脂族或芳族醇反应，所述量在根据式（I）计算的摩尔当量的脂族或芳族醇的可接受范围内：AlKanol = 2·[（ （H 2 O）/支撑体] [mmole·gel MgR / g·支撑体]（I）其中Equ Alkanol =摩尔当量 脂族或芳族链烷醇相对于镁 - 有机前体的摩尔量（毫摩尔MgR / g载体）=每克微粒固体载体的镁 - 有机前体的毫摩尔％wt％（H 2 O）/载体=物理吸附水的重量百分数 在固体载体上，并且所述镁有机前体化合物转化为镁 - 氧化合物。

    Ziegler-Natta catalyst, preparation, and use for the polymerization of alkenes
    7.
    发明授权
    Ziegler-Natta catalyst, preparation, and use for the polymerization of alkenes 有权

    公开(公告)号：US07329626B2

    公开(公告)日：2008-02-12

    申请号：US10935211

    申请日：2004-09-07

    申请人： Frank Wolf Spaether ,  David Andrew Presken

    发明人： Frank Wolf Spaether ,  David Andrew Presken

    IPC分类号： B01J37/00 ,  C08F4/02

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/025 ,  C08F4/6546 ,  C08F4/651 ,  C08F2500/12

    摘要： A method for making a solid catalytic component for a Ziegler-Natta catalyst includes contacting a particulate porous support with a solution of a hydrocarbon soluble organomagnesium precursor compound in a hydrocarbon solvent; and reacting said hydrocarbon soluble organo-magnesium precursor compound with an amount of aliphatic or aromatic alcohol, said amount being within an acceptable range of a molar equivalent of aliphatic or aromatic alcohol calculated according to formula (I): Equ Alkanol = 2 ⁢ · [ ( mmole ⁢ ⁢ MgR ⁢ / ⁢ g ⁢ ⁢ support ) - 2.1 - 0.55 ⁢ · ⁢ wt ⁢ ⁢ % ⁢ ⁢ ( H 2 ⁢ O ) ⁢ / ⁢ support ] [ mmole ⁢ ⁢ MgR ⁢ / ⁢ g ⁢ ⁢ support ] ( I ) wherein EquAlkanol=molar equivalents of aliphatic or aromatic alkanol relative to the molar amount of magnesium-organic precursor, (mmole MgR/g support)=mmoles of magnesium-organic precursor per gram of particulate solid support, wt % (H2O)/support=weight percent of physically adsorbed water on the solid support, and said magnesium organic precursor compound being converted to a magnesium-oxygen compound.

    Ziegler-Natta catalyst and methods of making and using same
    8.
    发明授权
    Ziegler-Natta catalyst and methods of making and using same 失效
    齐格勒 - 纳塔催化剂及其制备和使用方法

    公开(公告)号：US06831032B2

    公开(公告)日：2004-12-14

    申请号：US10223561

    申请日：2002-08-19

    申请人： Wolf Spaether

    发明人： Wolf Spaether

    IPC分类号： B01J3100

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6546 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/24

    摘要： A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining a porous particulate support with a magnesium source in a hydrocarbon solvent to form a mixture, the magnesium source including a hydrocarbon soluble organomagnesium compound and a hydrocarbon insoluble anhydrous inorganic magnesium-halogen compound. The organomagnesium compound is halogenated and the mixture is reacted with a titanium compound or vanadium compound to form the solid catalyst component. The solid catalyst component is then recovered and combined with an organoaluminum cocatalyst to form a Ziegler-Natta catalyst which is advantageously used for the polymerization of olefins, particularly alk-1-enes such as ethylene, propylene, 1-butene, and the like. The catalyst can optionally include internal and external electron donors.

    摘要翻译： 制备用于齐格勒 - 纳塔催化剂的固体催化剂组分的方法包括在烃溶剂中将多孔颗粒载体与镁源组合以形成混合物，所述镁源包括可溶于烃的有机镁化合物和不溶于烃的无水无机无机物 镁 - 卤素化合物。 将有机镁化合物卤化，并将混合物与钛化合物或钒化合物反应形成固体催化剂组分。 然后回收固体催化剂组分并与有机铝助催化剂组合以形成齐格勒 - 纳塔催化剂，该催化剂有利地用于烯烃聚合，特别是烯-1-烯如乙烯，丙烯，1-丁烯等。 催化剂可以任选地包括内部和外部电子给体。