Invention Grant
US06960279B2 Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith 失效
使用选择的聚合抑制剂和用其制备的聚合物稳定乙烯基芳族单体的方法

Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
Abstract:
Disclosed is the observation that 7-aryl-quinone methides and 4-tert-butylcatechol, when used in combination in a vinyl aromatic monomer to inhibit polymerization,do not inhibit polymerization to the same extend as each would if used separately. Stated another way, a phenomenon has been observed that when these two compounds are used together, they can, to a large extent, render each other unable to inhibit polymerization in a vinyl aromatic monomer. Also disclosed are methods of preventing adverse results of this interaction when undesired and a method of using this interaction to prepare a reactive vinyl aromatic monomer having a concentration of 4-tert-butylcatechol that would otherwise inhibit polymerization. The invention is disclosed to be useful with the production and storage of any vinyl aromatic monomer and is disclosed to be particularly useful with the production and storage of styrene monomer.
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