摘要:
A process for inhibiting the polymerization of cyclopentadiene compounds (B) by contacting the cyclopentadiene compound with a quinone methide compound (A) of structure (I), Compositions (AB) comprising (A) and (B) are also provided.
摘要:
The invention relates to a method for preserving peptides or proteins over long periods of time. The invention also relates to the use of the preservation method for the transport of labeled peptides or proteins without requiring refrigeration, as well as to a set of tools for implementing said method.
摘要:
The present invention provides a method for producing acryl syrup by bulk polymerization, comprising a step of preparing a mixture comprising monomer component and 2,4-diphenyl-4methyl-1-pentene; a step of heating the mixture to the initial reaction temperature; and a step of adding an polymerization initiator having the half-life of not more than 30 minutes at 5-80° C., wherein the initial reaction temperature is controlled so that the polymerization initiator has the half-life of up to 30 minutes. The method of the present invention has such advantages that reaction runaway does not occur, the control of molecular weight and conversion rate is possible even at low exothermic temperature, and a partially polymerized acryl syrup can also be prepared therefrom.
摘要:
The present invention relates to a polymer bead material that are characterised by having pore sizes that can be pre-determined and that can be obtained with a narrow distribution of such pore sizes created by use of sacrificial filler materials within the polymer material. The invention also discloses processes for production of the material as spherical or approximately spherical beads or resins with predefined sizes. Also, the invention relates to the preparation of molecularly imprinted polymer materials that are created by the said method. Further the invention relates to the use of said polymer materials for separation, detection, catalysis or entrapment of chemicals, metal ions, inorganic compounds, drags, peptides, proteins, DNA, natural and artificial polymers, natural or artificial compounds, food or pharma products, viruses, bacteria, cells and other entities.
摘要:
The present invention provides a method of producing porous spherical particles, which includes suspension polymerization of a multifunctional monomer having two or more vinyl groups and a vinyl monomer having one vinyl group in an aqueous medium in the presence of a porogen and a distribution stabilizer, wherein the distribution stabilizer is polyvinyl alcohol having a saponification degree of 75 to 85 mol %. According to the method of the present invention, generation of particle agglomerates and large particles can be suppressed and porous spherical particles having a desired average particle size and a narrow particle size distribution can be conveniently produced.
摘要:
The instant invention relates to multifunctional alkoxyamines based on polyalkylpiperidines, polyalkylpiperazinones and polyalkylmorpholinones and their use as polymerization regulatros/initiators. Further subjects of the invention are a polymerizable composition comprising an ethylenically unsaturated monomer or oligomer and the alkoxyamine compound as well as a process for polymerization and a process for preparation of the compounds.
摘要:
A polymeric, phosphorus-containing composition made by heating, in the presence of an initiator, preferably a free radical initiator, and optionally in the presence of one or more comonomers, at least one substituted phosphonylated 2,2′-dihydroxyl-1,1′-binaphthalene or at least one substituted 2,2′-dihydroxyl-1,1′-biphenylene.
摘要:
A process for the preparation of linear polymers or block copolymers of styrene by anionic polymerization comprises carrying out the chain termination with an n-alkyl glycidyl ether or a dialkyl ketone.
摘要:
A process for preparing syndiotactic polymers of vinylaromatic monomers having improved melt flowability comprising contacting one or more vinylaromatic monomers with a catalyst system comprising a titanium coordination complex capable of preparing syndiotactic vinylaromatic polymers under addition polymerization conditions in the presence of hydrogen gas at a hydrogen partial pressure from 0.1 to less than 10 kPa.
摘要:
The present invention provides a positive photoresist composition comprising an alkali-soluble resin containing a copolymer of p-vinylphenol or a derivative thereof and styrene, a dissolution inhibitor and a photo-induced acid precursor. This positive photoresist composition exhibits excellent sensitivity and resolution while maintaining excellence in other properties such as heat resistance, film thickness retention, adhesion and profile, in far ultraviolet ray lithography.