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公开(公告)号：US11236182B2
公开(公告)日：2022-02-01
申请号：US16977287
申请日：2019-03-25
IPC分类号： C08F10/02 , C08F2/06 , C08F6/02 , C08F2/42 , C08F110/14
摘要： A solution polymerization process for producing ethylene-based polymer includes introducing ethylene monomer, hydrocarbon solvent, and Ziegler-Natta catalyst into an entrance of a solution polymerization reactor. An ethylene-based polymer is produced by solution polymerizing the ethylene monomer in hydrocarbon solvent. Subsequently, a catalyst deactivator is introduced into x the exit of the solution polymerization reactor, thereby producing hydrochloric acid byproduct. The catalyst deactivator includes long chain carboxylate and at least one cation selected from Groups 1, 2, and 12 of the IUPAC periodic table, with the exception of calcium. The catalyst deactivator reduces the effectiveness of the Ziegler-Natta catalyst and neutralizes the hydrochloric acid by forming a chloride salt other than calcium chloride.
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公开(公告)号：US11059931B2
公开(公告)日：2021-07-13
申请号：US16640901
申请日：2018-08-29
发明人： Michiel Verswyvel , Norbert Niessner , Rainer Moors , Konrad Knoll , Bart Van-Den-Bossche , Christof Camerlinck
IPC分类号： C08F297/04 , B01J4/00 , B01J19/00 , B01J19/18 , C08F2/01 , C08F2/08 , C08F2/42 , C08F6/06 , C08F112/08
摘要： Process for the preparation of styrenic polymers having an improved color stability by anionic polymerization wherein the obtained terminated polymer solution is fed to a dispersing device to which water is added, fed to a buffer vessel and then is impregnated in a static mixer by addition of further water, carbon dioxide and one or more stabilizers.
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公开(公告)号：US11059914B2
公开(公告)日：2021-07-13
申请号：US16472175
申请日：2017-12-20
摘要： A process for the continuous synthesis of a diene elastomer is provided. The synthesis is conducted by means of n reactors r1 to rn, considered to be continuous stirred-tank reactors, which are equipped with an internal stirring system. The reactors are arranged in series, n varying from 2 to 15, preferably from 2 to 9. The reactor r1 is fed by an input solution comprising a solvent, one or more monomer(s), an anionic polymerization initiator chosen from lithium amides and a polar agent. The conversion by weight C1 in the first reactor is less than 70%, and the total conversion by weight Cn at the outlet of the reactor rn is greater than or equal to 70%.
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公开(公告)号：US11046793B2
公开(公告)日：2021-06-29
申请号：US16260545
申请日：2019-01-29
发明人： Jay L. Reimers , Yifeng Hong , John R. Hagadorn
IPC分类号： C08F2/42 , C08F10/02 , C08F10/06 , C08K3/36 , C08K9/06 , C08F6/10 , C08F6/02 , C08F6/00 , C08F2/38
摘要： This disclosure describes polymerization processes and processes for quenching polymerization reactions using reactive particulates, such as amorphous silica, as quenching agents, typically in solution or bulk polymerization processes.
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5.发明授权公开(公告)号：US10988561B2
公开(公告)日：2021-04-27
申请号：US15743781
申请日：2016-11-15
申请人： QINGDAO UNIVERSITY OF SCIENCE AND TECHNOLOGY , SHANDONG HUAJU POLYMER MATERIALS CO., LTD. , CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE CO., LTD.
发明人： Aihua He , Yunsheng Ma , Huafeng Shao , Gang Yao , Chenguang Liu , Bo Luan , Riguo Wang
IPC分类号： C08F236/06 , C08F236/08 , C08F2/01 , C08F2/02 , C08F2/42 , C08F4/642 , C08C4/00 , B01D3/00 , B01D3/14 , B01J8/00
摘要： A method for industrial production of a butadiene-isoprene copolymer rubber having a trans-1,4-structure (TBIR) and an apparatus for implementing the method. The production method includes: pumping a predetermined amount of a butadiene and an isoprene into a polymerization reactor, and performing bulk polymerization in the presence of a catalyst to obtain TBIR; performing extrusion, devolatilization, granulation and drying on the produced TBIR, and then packaging the produced TBIR; and separating unreacted monomers by a recovery and separation device followed by separately refining the unreacted monomers, and then returning the unreacted monomers to a batching device or a storage tank. The production apparatus has a recovery and refining unit, a polymerization unit, a post-treatment unit and a utility unit. By the production apparatus and the production method industrial production of TBIR by bulk polymerization is realized.
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公开(公告)号：US10723836B2
公开(公告)日：2020-07-28
申请号：US15565334
申请日：2016-04-05
申请人： Bostik SA
IPC分类号： C08G61/08 , C07D317/38 , C08G61/12 , C08G71/04 , C08G61/06 , C08F2/42 , C08G61/04 , C08F2/40 , C08F2/38 , C08F32/04
摘要： The invention relates to a hydrocarbon polymer comprising two exo-vinylene cyclic carbonate terminal groups, of formula (1), production method thereof and use of same for the production of coating, mastic and adhesive compositions.
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公开(公告)号：US10654949B2
公开(公告)日：2020-05-19
申请号：US16047052
申请日：2018-07-27
发明人： Jay L. Reimers , Yifeng Hong , John R. Hagadorn
摘要： This disclosure describes polymerization processes and processes for quenching polymerization reactions using reactive particulates, such as high molecular weight functionalized olefin copolymers, as quenching agents, typically in solution or bulk polymerization processes.
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公开(公告)号：US10544239B2
公开(公告)日：2020-01-28
申请号：US14966015
申请日：2015-12-11
发明人： Quanchang Li , David Charles Calabro , Mobae Amin Afeworki , Simon Christopher Weston , Matcheld Maria Wilfried Mertens , Tilman Wolfram Beutel , Wenyih Frank Lai , Paul Podsiadlo , Jean Willem Lodewijk Beeckman
IPC分类号： C10G45/52 , B01D15/00 , C08F10/02 , B01J31/06 , B01J35/10 , C08G77/58 , C08G77/50 , B01J20/08 , B01J20/28 , B01J37/03 , B01J20/06 , B01J20/10 , B01J20/26 , B01J20/286 , B01J20/30 , B01J20/32 , B01D53/22 , B01J23/42 , B01J31/12 , C01B37/00 , C01B39/00 , C08G77/60 , C08F2/00 , C08F2/10 , C08F2/42 , C10G25/00 , C10G35/06 , C10G45/00 , C10G45/04 , C10G45/34 , C10G45/44 , C10G45/46 , C10G45/60 , C10G45/64 , C10G47/02 , C10G50/00 , C10M177/00 , C10K1/32 , B01J29/03 , B01D53/04 , B01D53/047 , B01D53/02 , B01J23/44 , C10M101/02 , C07F7/00 , C08F4/659 , C08F4/6592
摘要： Organosilica materials, which are a polymer of at least one independent monomer of Formula [Z1OZ2OSiCH2]3 (I), wherein each Z1 and Z2 independently represent a hydrogen atom, a C1-C4 alkyl group or a bond to a silicon atom of another monomer and at least one other trivalent metal oxide monomer are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for catalysis etc., are also provided herein.
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公开(公告)号：US10450392B2
公开(公告)日：2019-10-22
申请号：US15641876
申请日：2017-07-05
IPC分类号： C08F210/06 , C08F2/42 , C08F6/00
摘要： This disclosure describes polymerization processes and processes for quenching polymerization reactions using high molecular weight polyhydric quenching agents.
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公开(公告)号：US10266622B2
公开(公告)日：2019-04-23
申请号：US15526529
申请日：2015-12-11
发明人： Matthew W. Holtcamp , Matthew S. Bedoya , Charles J. Harlan , Quanchang Li , Machteld M. W. Mertens
IPC分类号： C08F4/76 , C08F4/64 , C08F10/02 , B01J31/06 , B01J35/10 , C08G77/58 , C08G77/50 , B01J20/08 , B01J20/28 , B01D53/04 , B01D53/047 , B01J20/10 , B01D53/02 , B01D15/00 , B01J37/03 , B01J20/06 , B01J20/26 , B01J20/286 , B01J20/30 , B01J20/32 , B01D53/22 , B01J23/42 , B01J23/44 , B01J31/12 , C01B37/00 , C01B39/00 , C08G77/60 , C08F2/00 , C08F2/10 , C08F2/42 , C10G25/00 , C10G35/06 , C10G45/00 , C10G45/04 , C10G45/34 , C10G45/44 , C10G45/46 , C10G45/60 , C10G45/64 , C10G47/02 , C10G50/00 , C10M177/00 , C10K1/32 , C10M101/02 , C07F7/00 , C08F4/659 , C08F4/6592 , B01J29/03
摘要： A catalyst system comprising a combination of: 1) one or more catalyst compounds having at least one nitrogen linkage and at least one oxygen linkage to a transition metal; 2) a support comprising an organosilica material, which is a mesoporous organosilica material; and 3) an optional activator. Useful catalysts include ONNO-type transition metal catalysts, ONYO-Type transition metal catalysts, and/or oxadiazole transition metal catalysts. The organosilica material is a polymer of at least one monomer of Formula [z′OZ2 SiCH2]3(l), where Z1 represents a hydrogen atom, a C1-C4alkyl group, or a bond to a silicon atom of another monomer and Z2 represents a hydroxyl group, a C1-C4alkoxy group, a C1-C6alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.
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