发明授权
US07381585B2 Hetero diels-alder adducts of pentacene as soluble precursors of pentacene
有权
并五苯作为并五苯的可溶性前体的异狄氏al醛加成物
- 专利标题： Hetero diels-alder adducts of pentacene as soluble precursors of pentacene
- 专利标题（中）： 并五苯作为并五苯的可溶性前体的异狄氏al醛加成物
-
申请号： US11526943申请日： 2006-09-26
-
公开(公告)号： US07381585B2公开(公告)日： 2008-06-03
- 发明人: Ali Afzali-Ardakani , Tricia L Breen , Christos D Dimitrakopoulos
- 申请人： Ali Afzali-Ardakani , Tricia L Breen , Christos D Dimitrakopoulos
- 申请人地址： US NY Armonk
- 专利权人： International Business Machines Corporation
- 当前专利权人： International Business Machines Corporation
- 当前专利权人地址： US NY Armonk
- 代理机构： Ohlandt, Greeley, Ruggiero & Perle, L.L.P.
- 代理商 Daniel P. Morris, Esq.
- 主分类号： H01L51/40
- IPC分类号： H01L51/40
摘要：
The present invention describes organic solvent-soluble Diels-Alder adducts of polycyclic aromatic compounds, such as, oligothiophene, perylene, benzo[ghi]perylene, coronene and polyacenes, with variety of dienophiles containing at least one heteroatom and in some cases two heteroatoms bonded to aromatic moiety, such as, thioxomalonates, azodicarboxylates, thialdehyde, acylnitroso and N-sulfinylamides. The Diels-Alder adducts are prepared by a simple, one step cycloaddition reaction of the polycyclic aromatic compounds, such as, pentacene, or other fused aromatic compounds, with heterodienophiles. The Diels-Alder adducts according to the present invention all form soluble adducts with pentacene and can be converted back to pentacene by retro-Diels-Alder reaction at moderate (60-250° C.) temperatures both in bulk, in solution or as thin-films.
公开/授权文献
信息查询
IPC分类:
