Disclosed herein is an electrochromic device having the functionality of a secondary battery. The electrochromic device includes a plurality of secondary battery/display segments in which a double metal oxide layer comprising mesoporous metal oxide particles and macroporous metal oxide particles is disposed on a transparent electrode, and a cathode active material for a lithium secondary battery is disposed on a counter electrode to enable oxidation and reduction of lithium. Methods of manufacturing the electrochromic device are disclosed as well.