The method of manufacturing a film of thermotropic liquid crystal polymer includes extruding a thermotropic liquid crystal polymer of a kind in which any one of activation energies Ea1 and Ea2 of a melt viscosity is within the range of 30 to 90 kcal/mol, with the ratio (Ea1/Ea2) of the activation energy Ea1 relative to the activation energy Ea2 being within the range of 1 to 1.7. The activation energies Ea1 and Ea2 are measured by means of a capillary rheometer, including a nozzle of 1 mm in inner diameter and 10 mm in length disposed at an angle of introduction of 90° and a barrel of 9.55 mm in inner diameter, at respective shear rates of 243 seconds−1 and 2432 seconds−1 under a temperature ranging from the temperature [(Tm−10)° C.], which is lower by 10° C. than the melting point [(Tm)° C.] of the thermotropic liquid crystal polymer, to the temperature [(Tm+20)° C.], which is higher by 20° C. than the melting point [(Tm)° C.] of the thermotropic liquid crystal polymer. The thermotropic liquid crystal polymer also has a melt viscosity of not lower than 400 poises measured under predetermined conditions, and is extruded from a die that is heated to a temperature of predetermined range.