A charging device with boundary mode control is disclosed. The charging device includes a transformer, a power switch, a detection circuit and a pulse-width modulation (PWM) controller. The power switch is electrically connected to one end of a primary-side winding of the transformer. The detection circuit is electrically connected to the primary-side winding and the power switch. The detection circuit detects the resonance of the parasitic capacitance of the power switch, thereby generating a detection signal for boundary mode control. The PWM controller generates a pulse-width modulation signal for driving the power switch, and turns on the power switch according to the detection signal.