发明授权
US08252871B2 Catalyst for oligomerization of ethylene, method for its preparation and oligomerization process using the catalyst
有权
用于乙烯低聚的催化剂,其制备方法和使用该催化剂的低聚方法
- 专利标题: Catalyst for oligomerization of ethylene, method for its preparation and oligomerization process using the catalyst
- 专利标题(中): 用于乙烯低聚的催化剂,其制备方法和使用该催化剂的低聚方法
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申请号: US12736387申请日: 2009-03-04
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公开(公告)号: US08252871B2公开(公告)日: 2012-08-28
- 发明人: Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Anina Wöhl , Peter M. Fritz , Heinz Bölt , Wolfgang Müller , Florian Winkler , Anton Wellenhofer
- 申请人: Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Anina Wöhl , Peter M. Fritz , Heinz Bölt , Wolfgang Müller , Florian Winkler , Anton Wellenhofer
- 申请人地址: SA Riyadh DE Munich
- 专利权人: Saudi Basic Industries Corporation,Linde AG
- 当前专利权人: Saudi Basic Industries Corporation,Linde AG
- 当前专利权人地址: SA Riyadh DE Munich
- 代理机构: Kramer Levin Naftalis & Frankel LLP
- 优先权: EP08006851 20080404
- 国际申请: PCT/EP2009/001518 WO 20090304
- 国际公布: WO2009/121456 WO 20091008
- 主分类号: C08F112/14
- IPC分类号: C08F112/14 ; C08F8/40 ; C08F8/42 ; C07C2/24
摘要:
The present invention relates to a catalyst for oligomerization of ethylene, comprising a functionalized solid support; a ligand immobilized on the solid support by chemical bonding, wherein the immobilized ligand has the structure (R1)(R2)P—N(R3)—P(R4)—Y-support or (R1)(R2)P—N(R3)—P(R4)—N(R5)—P(R6)—Y-support, wherein R1, R2, R3, R4, R5 and R6 are independently selected from aliphatic group, aryl group, amino group and trimethylsilyl group and Y is the functional group of the support or a derivative thereof; and a chromium compound reacted with the ligand; and to a method for its preparation and a process for oligomerization of ethylene utilizing the catalyst.