公开(公告)号：US08093439B2

公开(公告)日：2012-01-10

申请号：US12083807

申请日：2006-09-26

申请人： Richard Schneider ,  Peter M. Fritz ,  Sebastian Muschelknautz ,  Heinz Bölt ,  Talal Ali ,  Fuad Mosa

发明人： Richard Schneider ,  Peter M. Fritz ,  Sebastian Muschelknautz ,  Heinz Bölt ,  Talal Ali ,  Fuad Mosa

IPC分类号： C07C2/02 ,  C08F6/00

CPC分类号： C07C2/30 ,  C08F210/16 ,  C08F2/00

摘要： The present invention relates to a method for oligomerization or polymerization of ethylene and/or alpha-olefins utilizing reactor equipment and other equipment wherein starting material comprising monomer(s), catalyst, cocatalyst and solvent is transferred to the reactor equipment via first piping, and product material comprising oligomer and/or polymer, non-reacted monomer(s), catalyst, cocatalyst and solvent is discharged from the reactor equipment via second piping, characterized in that the first piping, second piping, reactor equipment and/or other equipment are flushed with a product fraction obtained by said or a respective previous method prior to and/or after that oligomerization or polymerization method.

摘要翻译： 本发明涉及使用反应器设备和其他设备使乙烯和/或α-烯烃低聚或聚合的方法，其中包含单体，催化剂，助催化剂和溶剂的原料通过第一管道被转移到反应器设备中，以及 包含低聚物和/或聚合物，未反应的单体，催化剂，助催化剂和溶剂的产品材料经由第二管道从反应器设备排出，其特征在于，第一管道，第二管道，反应器设备和/或其他设备是 在所述低聚或聚合方法之前和/或之后，用所述或先前方法获得的产物级分冲洗。

公开(公告)号：US20090214405A1

公开(公告)日：2009-08-27

申请号：US12083806

申请日：2006-09-06

申请人： Richard Schneider ,  Peter M. Fritz ,  Sebastian Muschelknautz ,  Heinz Bölt ,  Talal Ali ,  Fuad Mosa

发明人： Richard Schneider ,  Peter M. Fritz ,  Sebastian Muschelknautz ,  Heinz Bölt ,  Talal Ali ,  Fuad Mosa

IPC分类号： B01J19/24

CPC分类号： C07C7/00 ,  B01J8/006 ,  B01J2208/00539 ,  C07C2/08 ,  C08F110/02 ,  C08F2500/02

摘要： The present invention relates to a bubble column reactor comprising a column reactor having a sparger plate dividing the column reactor into a top reaction compartment and a bottom compartment, characterized in that an inlet and outlet line for introducing and disposing a flushing medium are connected to the bottom compartment; and an operation method thereof.

摘要翻译： 本发明涉及一种鼓泡塔反应器，其包括具有将塔反应器分成顶部反应室和底部隔室的分布器板的塔式反应器，其特征在于用于引入和布置冲洗介质的入口和出口管线连接到 底部隔间 及其操作方法。

公开(公告)号：US08637721B2

公开(公告)日：2014-01-28

申请号：US12452594

申请日：2008-06-16

申请人： Peter M. Fritz ,  Heinz Bölt ,  Anina Wöhl ,  Wolfgang Müller ,  Florian Winkler ,  Anton Wellenhofer ,  Uwe Rosenthal ,  Bernd H. Müller ,  Marko Hapke ,  Normen Peulecke ,  Mohammed Hassan Al-Hazmi ,  Vugar O. Aliyev ,  Fuad Mohammed Mosa

发明人： Peter M. Fritz ,  Heinz Bölt ,  Anina Wöhl ,  Wolfgang Müller ,  Florian Winkler ,  Anton Wellenhofer ,  Uwe Rosenthal ,  Bernd H. Müller ,  Marko Hapke ,  Normen Peulecke ,  Mohammed Hassan Al-Hazmi ,  Vugar O. Aliyev ,  Fuad Mohammed Mosa

IPC分类号： C07C2/22 ,  B01J31/18

CPC分类号： B01J31/2495 ,  B01J31/143 ,  B01J31/1885 ,  B01J31/189 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/62 ,  C07C2/32 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/24 ,  C07F9/224 ,  C07F9/46 ,  C07F9/4883 ,  C07F9/65848 ,  C07F9/6587 ,  Y02P20/52 ,  C07C11/107

摘要： The present invention relates to a catalyst composition and a process for di-, tri- and/or tetramerization of ethylene, wherein the catalyst composition comprises a chromium compound, a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—N(R5)—H or (B) R1R2P—N(R3)—P(R4)—N(R5)—PR6R7, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNPNP-unit is member of a ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution and a co-catalyst or activator.

摘要翻译： 本发明涉及一种催化剂组合物和乙烯的二 - ，三 - 和/或四烯化方法，其中催化剂组合物包含铬化合物，通式结构的配体（A）R1R2P-N（R3）-P （R4）-N（R5）-H或（B）R1R2P-N（R3）-P（R4）-N（R5）-PR6R7或（A）和（B）的任何环状衍生物，其中至少一个 PNPN单元或PNPNP单元的P或N原子是环系的成员，环体系由一种或多种结构（A）或（B）的组成化合物通过取代和助催化剂或 活化剂。

公开(公告)号：US20110178355A1

公开(公告)日：2011-07-21

申请号：US12225395

申请日：2007-01-31

申请人： Peter M. Fritz ,  Wolfgang Müller ,  Florian Winnkler

发明人： Peter M. Fritz ,  Wolfgang Müller ,  Florian Winnkler

IPC分类号： C07C2/68 ,  B01J19/00 ,  C07C2/66

CPC分类号： C07C2/08 ,  C07C7/14883 ,  C07C11/02

摘要： The present invention relates to a method and a reactor system for preparing linear alpha-olefins by oligomerization of ethylene in the presence of an organic solvent and an oligomerization catalyst, wherein a product fraction of C10+ alpha-olefins contaminated with aromatic C9+ compounds is separated from a product main stream and transferred into a conversion reactor, where C10+ alpha-olefins and aromatic C9+ components are reacted in the presence of a Friedel-Crafts alkylation catalyst to produce aromatic C19+ compounds.

摘要翻译： 本发明涉及一种通过在有机溶剂和低聚催化剂存在下使乙烯低聚制备线性α-烯烃的方法和反应器系统，其中被芳族C 9+化合物污染的C10 +α-烯烃的产物级分与 产物主流并转移到转化反应器中，其中C 10+α-烯烃和芳族C 9+组分在Friedel-Crafts烷基化催化剂存在下反应以产生芳族C19 +化合物。

公开(公告)号：US20110054233A1

公开(公告)日：2011-03-03

申请号：US12735267

申请日：2008-12-18

申请人： Fuad Mousa ,  Mohammed Al-Hazmi ,  Abdullah Al-Thauyyan ,  Mohammed Al-Musned ,  Wolfgang Müller ,  Peter M. Fritz ,  Heinz Bölt ,  Anton Wellenhofer ,  Andreas Meiswinkel ,  Carsten Taube ,  Richard Schneider ,  Florian Winkler ,  Helmut Fritz ,  Karl-Heinz Hofmann ,  Hans-Jörg Zander ,  Peter Ulbrich ,  Jan Segatz

发明人： Fuad Mousa ,  Mohammed Al-Hazmi ,  Abdullah Al-Thauyyan ,  Mohammed Al-Musned ,  Wolfgang Müller ,  Peter M. Fritz ,  Heinz Bölt ,  Anton Wellenhofer ,  Andreas Meiswinkel ,  Carsten Taube ,  Richard Schneider ,  Florian Winkler ,  Helmut Fritz ,  Karl-Heinz Hofmann ,  Hans-Jörg Zander ,  Peter Ulbrich ,  Jan Segatz

IPC分类号： C07C2/08 ,  B01J19/00

CPC分类号： B01J19/18 ,  B01J19/1806 ,  C07C2/22 ,  C07C11/04 ,  C07C2521/06 ,  C07C2531/14 ,  Y02P20/52

摘要： The present invention relates to a method and a reactor system, for the oligomerization of ethylene, comprising oligomerizing ethylene in a reactor in the presence of a solvent and a catalyst composition to produce a liquid product stream comprising linear alpha-olefins, solvent and catalyst composition, and deactivating and extracting the catalyst composition in said liquid product stream by mixing it with a polar phase in a dynamic mixing device having rotor and stator elements comprising concentric tool rings.

摘要翻译： 本发明涉及用于乙烯低聚的方法和反应器系统，其包括在溶剂和催化剂组合物存在下在反应器中使乙烯低聚以产生包含线性α-烯烃，溶剂和催化剂组合物的液体产物流 并且通过在具有包括同心工具环的转子和定子元件的动态混合装置中将其与极性相混合来使所述液体产物流中的催化剂组合物失活和萃取。

公开(公告)号：US20110046429A1

公开(公告)日：2011-02-24

申请号：US12735585

申请日：2009-01-07

申请人： Vugar Aliyev ,  Fuda Mosa ,  Mohammed Al-Hazmi ,  Syriac Palackal ,  Ayed Al-ayed ,  Sultan Al-Otaibi ,  Mohammed Zahoor ,  Wolfgang Müller ,  Peter M. Fritz ,  Heinz Bölt ,  Anton Wellenhofer ,  Florian Winkler ,  Uwe Rosenthal ,  Hans-Jörg Zander ,  Normen Peulecke ,  Bernd H. Müller ,  Karl-Heinz Hofmann ,  Helmut Fritz ,  Carsten Taube ,  Andreas Meiswinkel ,  Richard Schneider ,  Anina Woehl

发明人： Vugar Aliyev ,  Fuda Mosa ,  Mohammed Al-Hazmi ,  Syriac Palackal ,  Ayed Al-ayed ,  Sultan Al-Otaibi ,  Mohammed Zahoor ,  Wolfgang Müller ,  Peter M. Fritz ,  Heinz Bölt ,  Anton Wellenhofer ,  Florian Winkler ,  Uwe Rosenthal ,  Hans-Jörg Zander ,  Normen Peulecke ,  Bernd H. Müller ,  Karl-Heinz Hofmann ,  Helmut Fritz ,  Carsten Taube ,  Andreas Meiswinkel ,  Richard Schneider ,  Anina Woehl

IPC分类号： C07C2/02

CPC分类号： C07C2/30 ,  C07C2531/025 ,  C07C2531/04 ,  C07C2531/14

摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of solvent and homogenous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, ethylene, and catalyst from the reactor via a reactor outlet piping system, (iv) transferring the reactor outlet stream to a catalyst deactivation and removal step, and (v) deactivating and removing the catalyst from the reactor outlet stream, characterized in that at least one organic amine is added into the oligomerization reactor and/or into the reactor outlet piping system.

摘要翻译： 本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，其包括以下步骤：（i）将乙烯，溶剂和催化剂加入到低聚反应器中，（ii ）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，直链α-烯烃，乙烯和催化剂的反应器出口流，（iv）将反应器出口流转移到催化剂失活 和（v）从反应器出口流中去活化和除去催化剂，其特征在于将至少一种有机胺加入到低聚反应器和/或反应器出口管道系统中。

公开(公告)号：US20100298618A1

公开(公告)日：2010-11-25

申请号：US12734770

申请日：2008-11-05

申请人： Vugar Aliyev ,  Mohammed Al-Hazmi ,  Fuad Mosa ,  Peter M. Fritz ,  Heinz Bölt ,  Anina Wöhl ,  Wolfgang Müller ,  Florian Winkler ,  Anton Wellenhofer ,  Uwe Rosenthal ,  Bernd H. Müller ,  Marko Hapke ,  Normen Peulecke

发明人： Vugar Aliyev ,  Mohammed Al-Hazmi ,  Fuad Mosa ,  Peter M. Fritz ,  Heinz Bölt ,  Anina Wöhl ,  Wolfgang Müller ,  Florian Winkler ,  Anton Wellenhofer ,  Uwe Rosenthal ,  Bernd H. Müller ,  Marko Hapke ,  Normen Peulecke

IPC分类号： C07C2/24 ,  B01J31/18 ,  B01J31/14

CPC分类号： B01J31/189 ,  B01J31/143 ,  B01J31/188 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/62 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/24

摘要： The present invention relates to a catalyst composition comprising: (a) a binuclear chromium(II) complex; (b) a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—N(R5)—H or (B) R1R2P—N(R3)—P(R4)—N(R5)—PR6R7, wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from halogen, amino, trimethylsilyl, C1-C10-alkyl, aryl and substituted aryl, wherein the PNPN- or PNPNP-unit is optionally part of a ring system; and (c) an activator or co-catalyst, as well as to a process for oligomerization of ethylene.

摘要翻译： 本发明涉及一种催化剂组合物，其包含：（a）双核铬（II）络合物; （R）R（R）-N（R 5）-H或（B）R 1 R 2 P -N（R 3）-P（R 4）-N（R 5） -PR 6 R 7，其中R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自卤素，氨基，三甲基甲硅烷基，C 1 -C 10 - 烷基，芳基和取代的芳基，其中PNPN-或PNPNP-单元任选地是 环系; 和（c）活化剂或助催化剂，以及乙烯低聚方法。

公开(公告)号：US20090318639A1

公开(公告)日：2009-12-24

申请号：US12083807

申请日：2006-09-26

申请人： Richard Schneider ,  Peter M. Fritz ,  Sebastian Muschelknautz ,  Heinz Bölt ,  Talal Ali ,  Fuad Mosa

发明人： Richard Schneider ,  Peter M. Fritz ,  Sebastian Muschelknautz ,  Heinz Bölt ,  Talal Ali ,  Fuad Mosa

IPC分类号： C08F2/00

CPC分类号： C07C2/30 ,  C08F210/16 ,  C08F2/00

摘要： The present invention relates to a method for oligomerization or polymerization of ethylene and/or alpha-olefins utilizing reactor equipment and other equipment wherein starting material comprising monomer(s), catalyst, cocatalyst and solvent is transferred to the reactor equipment via first piping, and product material comprising oligomer and/or polymer, non-reacted monomer(s), catalyst, cocatalyst and solvent is discharged from the reactor equipment via second piping, characterized in that the first piping, second piping, reactor equipment and/or other equipment are flushed with a product fraction obtained by said or a respective previous method prior to and/or after that oligomerization or polymerization method.

摘要翻译： 本发明涉及使用反应器设备和其他设备使乙烯和/或α-烯烃低聚或聚合的方法，其中包含单体，催化剂，助催化剂和溶剂的原料通过第一管道被转移到反应器设备中，以及 包含低聚物和/或聚合物，未反应的单体，催化剂，助催化剂和溶剂的产品材料经由第二管道从反应器设备排出，其特征在于，第一管道，第二管道，反应器设备和/或其他设备是 在所述低聚或聚合方法之前和/或之后，用所述或先前方法获得的产物级分冲洗。

公开(公告)号：US09593055B2

公开(公告)日：2017-03-14

申请号：US12735585

申请日：2009-01-07

申请人： Vugar Aliyev ,  Fuad Mosa ,  Mohammed Al-Hazmi ,  Syriac Palackal ,  Ayed Al-Ayed ,  Sultan Al-Otaibi ,  Mohammed Zahoor ,  Wolfgang Müller ,  Peter M. Fritz ,  Heinz Bölt ,  Anton Wellenhofer ,  Florian Winkler ,  Uwe Rosenthal ,  Hans-Jörg Zander ,  Normen Peulecke ,  Bernd H. Müller ,  Karl-Heinz Hofmann ,  Helmut Fritz ,  Carsten Taube ,  Andreas Meiswinkel ,  Richard Schneider ,  Anina Woehl

发明人： Vugar Aliyev ,  Fuad Mosa ,  Mohammed Al-Hazmi ,  Syriac Palackal ,  Ayed Al-Ayed ,  Sultan Al-Otaibi ,  Mohammed Zahoor ,  Wolfgang Müller ,  Peter M. Fritz ,  Heinz Bölt ,  Anton Wellenhofer ,  Florian Winkler ,  Uwe Rosenthal ,  Hans-Jörg Zander ,  Normen Peulecke ,  Bernd H. Müller ,  Karl-Heinz Hofmann ,  Helmut Fritz ,  Carsten Taube ,  Andreas Meiswinkel ,  Richard Schneider ,  Anina Woehl

IPC分类号： C07C2/02 ,  C07C2/04 ,  C07C2/08 ,  C07C2/30

CPC分类号： C07C2/30 ,  C07C2531/025 ,  C07C2531/04 ,  C07C2531/14

摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of solvent and homogenous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, ethylene, and catalyst from the reactor via a reactor outlet piping system, (iv) transferring the reactor outlet stream to a catalyst deactivation and removal step, and (v) deactivating and removing the catalyst from the reactor outlet stream, characterized in that at least one organic amine is added into the oligomerization reactor and/or into the reactor outlet piping system.

摘要翻译： 本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，其包括以下步骤：（i）将乙烯，溶剂和催化剂加入到低聚反应器中，（ii ）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，直链α-烯烃，乙烯和催化剂的反应器出口流，（iv）将反应器出口流转移到催化剂失活 和（v）从反应器出口流中去活化和除去催化剂，其特征在于将至少一种有机胺加入到低聚反应器和/或反应器出口管道系统中。

公开(公告)号：US08809613B2

公开(公告)日：2014-08-19

申请号：US13386618

申请日：2010-05-28

申请人： Peter M. Fritz ,  Heinz Bölt ,  Andreas Meiswinkel ,  Carsten Taube ,  Florian Winkler ,  Volker Göke ,  Wolfgang Müller ,  Anina Wöhl ,  Richard Schneider ,  Uwe Rosenthal ,  Helmut Fritz ,  Bernd H. Müller ,  Normen Peulecke ,  Stephan Peitz ,  Bhaskar Reddy Aluri ,  Mohammed Al-Hazmi ,  Shahid Majeed Azam ,  Fuad Mosa ,  Abdullah Al-Dugathier

发明人： Peter M. Fritz ,  Heinz Bölt ,  Andreas Meiswinkel ,  Carsten Taube ,  Florian Winkler ,  Volker Göke ,  Wolfgang Müller ,  Anina Wöhl ,  Richard Schneider ,  Uwe Rosenthal ,  Helmut Fritz ,  Bernd H. Müller ,  Normen Peulecke ,  Stephan Peitz ,  Bhaskar Reddy Aluri ,  Mohammed Al-Hazmi ,  Shahid Majeed Azam ,  Fuad Mosa ,  Abdullah Al-Dugathier

IPC分类号： C07C2/08

CPC分类号： C07C2/30 ,  C07C2531/025 ,  C07C2531/04 ,  C07C2531/14 ,  C07C11/02

摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of a solvent and homogeneous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, optionally unreacted ethylene and catalyst from the reactor via a reactor outlet piping system, (iv) dosing at least one additive selected from the group consisting of alcohols, poly-ethylene glycols, polyethylene glycol monoethers, polyethylene glycol diethers, polyamines, amines, amino alcohols and surfactants, (v) transferring the reactor outlet stream containing the additive to a catalyst deactivation and removal section, and (vi) deactivating the catalyst with caustic and removing the deactivated catalyst from the reactor outlet stream, wherein the residence time of the additive in the reactor outlet stream prior to mixing with caustic is at least 1 second preferably at least 5 seconds, more preferably at least 10 seconds.

摘要翻译： 本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，包括以下步骤：（i）将乙烯，溶剂和催化剂进料到低聚反应器中（ ii）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，线性α-烯烃，任选未反应的乙烯和催化剂的反应器出口流，（iv）给予至少一种选自 由醇，聚乙二醇，聚乙二醇单醚，聚乙二醇二醚，多胺，胺，氨基醇和表面活性剂组成的组，（v）将含有添加剂的反应器出口流转移到催化剂失活和除去部分，和（vi ）用苛性碱使催化剂失活并从反应器出口流中除去失活的催化剂，其中添加剂在真空中的停留时间 在与苛性碱混合之前的出口流量为至少1秒，优选至少5秒，更优选至少10秒。