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1.发明授权Catalyst for oligomerization of ethylene, method for its preparation and oligomerization process using the catalyst 有权用于乙烯低聚的催化剂，其制备方法和使用该催化剂的低聚方法公开(公告)号：US08252871B2
公开(公告)日：2012-08-28
申请号：US12736387
申请日：2009-03-04
申请人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Anina Wöhl , Peter M. Fritz , Heinz Bölt , Wolfgang Müller , Florian Winkler , Anton Wellenhofer
发明人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Anina Wöhl , Peter M. Fritz , Heinz Bölt , Wolfgang Müller , Florian Winkler , Anton Wellenhofer
IPC分类号： C08F112/14 , C08F8/40 , C08F8/42 , C07C2/24
CPC分类号： B01J31/1658 , B01J31/189 , B01J2231/20 , B01J2531/62
摘要： The present invention relates to a catalyst for oligomerization of ethylene, comprising a functionalized solid support; a ligand immobilized on the solid support by chemical bonding, wherein the immobilized ligand has the structure (R1)(R2)P—N(R3)—P(R4)—Y-support or (R1)(R2)P—N(R3)—P(R4)—N(R5)—P(R6)—Y-support, wherein R1, R2, R3, R4, R5 and R6 are independently selected from aliphatic group, aryl group, amino group and trimethylsilyl group and Y is the functional group of the support or a derivative thereof; and a chromium compound reacted with the ligand; and to a method for its preparation and a process for oligomerization of ethylene utilizing the catalyst.
摘要翻译： 本发明涉及乙烯低聚催化剂，其包括官能化固体载体; 通过化学键合固定在固体支持物上的配体，其中固定的配体具有结构（R1）（R2）P-N（R3）-P（R4）-Y-支持或（R1）（R2）P-N（ R3）-P（R4）-N（R5）-P（R6）-Y-支持物，其中R1，R2，R3，R4，R5和R6独立地选自脂族基团，芳基，氨基和三甲基甲硅烷基， Y是支持体的官能团或其衍生物; 和与配体反应的铬化合物; 以及其制备方法和利用该催化剂使乙烯低聚的方法。
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2.发明授权Catalyst composition and process for di-, tri- and/or tetramerization of ethylene 有权催化剂组合物和乙烯二，三和/或四聚的方法公开(公告)号：US08637721B2
公开(公告)日：2014-01-28
申请号：US12452594
申请日：2008-06-16
申请人： Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Mohammed Hassan Al-Hazmi , Vugar O. Aliyev , Fuad Mohammed Mosa
发明人： Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Mohammed Hassan Al-Hazmi , Vugar O. Aliyev , Fuad Mohammed Mosa
CPC分类号： B01J31/2495 , B01J31/143 , B01J31/1885 , B01J31/189 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/224 , C07F9/46 , C07F9/4883 , C07F9/65848 , C07F9/6587 , Y02P20/52 , C07C11/107
摘要： The present invention relates to a catalyst composition and a process for di-, tri- and/or tetramerization of ethylene, wherein the catalyst composition comprises a chromium compound, a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—N(R5)—H or (B) R1R2P—N(R3)—P(R4)—N(R5)—PR6R7, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNPNP-unit is member of a ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution and a co-catalyst or activator.
摘要翻译： 本发明涉及一种催化剂组合物和乙烯的二 - ，三 - 和/或四烯化方法，其中催化剂组合物包含铬化合物，通式结构的配体（A）R1R2P-N（R3）-P （R4）-N（R5）-H或（B）R1R2P-N（R3）-P（R4）-N（R5）-PR6R7或（A）和（B）的任何环状衍生物，其中至少一个 PNPN单元或PNPNP单元的P或N原子是环系的成员，环体系由一种或多种结构（A）或（B）的组成化合物通过取代和助催化剂或 活化剂。
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公开(公告)号：US20100298618A1
公开(公告)日：2010-11-25
申请号：US12734770
申请日：2008-11-05
申请人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke
发明人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke
CPC分类号： B01J31/189 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/36 , C07C2531/14 , C07C2531/24
摘要： The present invention relates to a catalyst composition comprising: (a) a binuclear chromium(II) complex; (b) a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—N(R5)—H or (B) R1R2P—N(R3)—P(R4)—N(R5)—PR6R7, wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from halogen, amino, trimethylsilyl, C1-C10-alkyl, aryl and substituted aryl, wherein the PNPN- or PNPNP-unit is optionally part of a ring system; and (c) an activator or co-catalyst, as well as to a process for oligomerization of ethylene.
摘要翻译： 本发明涉及一种催化剂组合物，其包含：（a）双核铬（II）络合物; （R）R（R）-N（R 5）-H或（B）R 1 R 2 P -N（R 3）-P（R 4）-N（R 5） -PR 6 R 7，其中R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自卤素，氨基，三甲基甲硅烷基，C 1 -C 10 - 烷基，芳基和取代的芳基，其中PNPN-或PNPNP-单元任选地是 环系; 和（c）活化剂或助催化剂，以及乙烯低聚方法。
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公开(公告)号：US08778827B2
公开(公告)日：2014-07-15
申请号：US12734770
申请日：2008-11-05
申请人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke
发明人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke
CPC分类号： B01J31/189 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/36 , C07C2531/14 , C07C2531/24
摘要： The present invention relates to a catalyst composition comprising: (a) a binuclear chromium(II) complex; (b) a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—N(R5)—H or (B) R1R2P—N(R3)—P(R4)—N(R5)—PR6R7, wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from halogen, amino, trimethylsilyl, C1-C10-alkyl, aryl and substituted aryl, wherein the PNPN- or PNPNP-unit is optionally part of a ring system; and (c) an activator or co-catalyst, as well as to a process for oligomerization of ethylene.
摘要翻译： 本发明涉及一种催化剂组合物，其包含：（a）双核铬（II）络合物; （R）R（R）-N（R 5）-H或（B）R 1 R 2 P -N（R 3）-P（R 4）-N（R 5） -PR 6 R 7，其中R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自卤素，氨基，三甲基甲硅烷基，C 1 -C 10 - 烷基，芳基和取代的芳基，其中PNPN-或PNPNP-单元任选地是 环系; 和（c）活化剂或助催化剂，以及乙烯低聚方法。
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5.发明申请CATALYST COMPOSITION AND PROCESS FOR DI-, TRI-AND/OR TETRAMERIZATION OF ETHYLENE 有权催化剂组合物和乙烯的二 - ，三 - 和/或四甲基化的方法公开(公告)号：US20100190939A1
公开(公告)日：2010-07-29
申请号：US12452594
申请日：2008-06-16
申请人： Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Mohammed Hassan Al-Hazmi , Vugar O. Aliyev , Fuad Mohammed Mosa
发明人： Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke , Mohammed Hassan Al-Hazmi , Vugar O. Aliyev , Fuad Mohammed Mosa
CPC分类号： B01J31/2495 , B01J31/143 , B01J31/1885 , B01J31/189 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07F9/224 , C07F9/46 , C07F9/4883 , C07F9/65848 , C07F9/6587 , Y02P20/52 , C07C11/107
摘要： The present invention relates to a catalyst composition and a process for di-, tri- and/or tetramerization of ethylene, wherein the catalyst composition comprises a chromium compound, a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—N(R5)—H or (B) R1R2P—N(R3)—P(R4)—N(R5)—PR6R7, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNPNP-unit is member of a ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution and a co-catalyst or activator.
摘要翻译： 本发明涉及一种催化剂组合物和乙烯的二 - ，三 - 和/或四烯化方法，其中催化剂组合物包含铬化合物，通式结构的配体（A）R1R2P-N（R3）-P （R4）-N（R5）-H或（B）R1R2P-N（R3）-P（R4）-N（R5）-PR6R7或（A）和（B）的任何环状衍生物，其中至少一个 PNPN单元或PNPNP单元的P或N原子是环系的成员，环体系由一种或多种结构（A）或（B）的组成化合物通过取代和助催化剂或 活化剂。
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