发明授权
US08324341B2 Agent serving as oxidant and dopant for conductive polymer production, an alcohol solution thereof, a conductive polymer synthesized by using the same, and a solid electrolytic capacitor using the conductive polymer as a solid electrolyte
有权
用作导电聚合物生产的氧化剂和掺杂剂,其醇溶液,使用它的合成的导电聚合物和使用导电聚合物作为固体电解质的固体电解电容器
- 专利标题: Agent serving as oxidant and dopant for conductive polymer production, an alcohol solution thereof, a conductive polymer synthesized by using the same, and a solid electrolytic capacitor using the conductive polymer as a solid electrolyte
- 专利标题(中): 用作导电聚合物生产的氧化剂和掺杂剂,其醇溶液,使用它的合成的导电聚合物和使用导电聚合物作为固体电解质的固体电解电容器
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申请号: US12522077申请日: 2008-06-17
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公开(公告)号: US08324341B2公开(公告)日: 2012-12-04
- 发明人: Ryousuke Sugihara , Masayuki Kondo , Yuhei Tsurumoto
- 申请人: Ryousuke Sugihara , Masayuki Kondo , Yuhei Tsurumoto
- 申请人地址: JP Osaka-shi
- 专利权人: Tayca Corporation
- 当前专利权人: Tayca Corporation
- 当前专利权人地址: JP Osaka-shi
- 代理机构: Westerman, Hattori, Daniels & Adrian, LLP
- 优先权: JP2007-167090 20070626
- 国际申请: PCT/JP2008/061013 WO 20080617
- 国际公布: WO2009/001707 WO 20081231
- 主分类号: C08G75/00
- IPC分类号: C08G75/00
摘要:
The present invention provides an agent serving as oxidant and dopant in which it does not generate precipitates in a state of an alcohol solution for a certain period of time and the oxidizing power is not too strong. By using the same, the present invention provides a conductive polymer having a high conductivity and heat resistance. By using the same, the present invention provides a solid electrolytic capacitor reliable under a high temperature condition. The present invention provides an agent serving as oxidant and dopant for conductive polymer production, the agent serving as oxidant and dopant comprising: a ferric salt of acids comprising a benzene sulfonic acid derivative represented by formula (1) and sulfuric acid. “R” represents an alkyl or alkoxy group having a carbon number of 1 to 4. More than 90 mole % of the benzene sulfonic acid derivative have R at the para position with respect to the SO3H group. Sulfuric acid is contained at 0.05 to 1.5 mass % in the acids. An alkali metal and alkali earth metal as an inorganic alkali component are included at a total content of 300 ppm or less (based on mass). ammonia and an amine as an organic alkali component are included at a total content of 0.01 mole % or less. A pH value is 1.5 to 3.0 when the agent serving as oxidant and dopant is made into an aqueous solution at a concentration of 8 mass %.
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