发明授权
- 专利标题: Primary allylic alcohol and Ag
- 专利标题(中): 初级烯丙醇和Ag
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申请号: US12526860申请日: 2008-02-15
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公开(公告)号: US08536341B2公开(公告)日: 2013-09-17
- 发明人: Werner Bonrath , Jean-Francois Eckhard , Manfred L. Eggersdorfer , Ramona Hinze , Wolfgang F. Hölderich , Michael H. Valkenberg
- 申请人: Werner Bonrath , Jean-Francois Eckhard , Manfred L. Eggersdorfer , Ramona Hinze , Wolfgang F. Hölderich , Michael H. Valkenberg
- 申请人地址: NL Heerlen
- 专利权人: DSM IP Assets B.V.
- 当前专利权人: DSM IP Assets B.V.
- 当前专利权人地址: NL Heerlen
- 代理机构: Nixon & Vanderhye P.C.
- 优先权: EP07003307 20070216
- 国际申请: PCT/EP2008/001169 WO 20080215
- 国际公布: WO2008/098774 WO 20080821
- 主分类号: C07D211/94
- IPC分类号: C07D211/94 ; C07C29/56
摘要:
The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2′,6,6′-tetra-methylpiperidin-1-oxyl) or its derivates and c) a co-oxidants selected from the group of peroxodisulfates (PDS), H2SO5, H2O2, NaOCl, O2, KOCl, and air.
公开/授权文献
- US20110015412A1 PRIMARY ALLYLIC ALCOHOL AND AG 公开/授权日:2011-01-20