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公开(公告)号:US08536341B2
公开(公告)日:2013-09-17
申请号:US12526860
申请日:2008-02-15
申请人: Werner Bonrath , Jean-Francois Eckhard , Manfred L. Eggersdorfer , Ramona Hinze , Wolfgang F. Hölderich , Michael H. Valkenberg
发明人: Werner Bonrath , Jean-Francois Eckhard , Manfred L. Eggersdorfer , Ramona Hinze , Wolfgang F. Hölderich , Michael H. Valkenberg
IPC分类号: C07D211/94 , C07C29/56
摘要: The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2′,6,6′-tetra-methylpiperidin-1-oxyl) or its derivates and c) a co-oxidants selected from the group of peroxodisulfates (PDS), H2SO5, H2O2, NaOCl, O2, KOCl, and air.
摘要翻译: 本发明涉及使一级烯丙基醇与含有a)选自Ag,Au,Ce,Mn,Ni,Ru,Re,Zn和Co的金属优选Ag和b)氧化剂 例如TEMPO(2,2',6,6'-四甲基哌啶-1-氧基)或其衍生物,和c)选自过氧二硫酸盐(PDS),H 2 SO 5,H 2 O 2,NaOCl,O 2,KOCl的共氧化剂 ,和空气。
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公开(公告)号:US20110015412A1
公开(公告)日:2011-01-20
申请号:US12526860
申请日:2008-02-15
申请人: Werner Bonrath , Jean-Francois Eckhardt , Manfred L. Eggersdorfer , Ramona Hinze , Wolfgang F. Hölderich , Michael H. Valkenberg
发明人: Werner Bonrath , Jean-Francois Eckhardt , Manfred L. Eggersdorfer , Ramona Hinze , Wolfgang F. Hölderich , Michael H. Valkenberg
摘要: The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2′,6,6′-tetra-methylpiperidin-1-oxyl) or its derivates and c) a co-oxidants selected from the group of peroxodisulfates (PDS), H2505, H2O2, NaOCl, O2, KOCl, and air.
摘要翻译: 本发明涉及使一级烯丙基醇与含有a)选自Ag,Au,Ce,Mn,Ni,Ru,Re,Zn和Co的金属优选Ag和b)氧化剂 例如TEMPO(2,2',6,6'-四甲基哌啶-1-氧基)或其衍生物,和c)选自过氧二硫酸盐(PDS),H 2 50 5,H 2 O 2,NaOCl,O 2,KOCl ,和空气。
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