A liquid crystal display device which can exhibit a blue phase stably is manufactured. A first substrate and a second substrate are attached by a sealant interposing a liquid crystal layer comprising a liquid crystal composition therebetween, an alignment state of the liquid crystal layer is set to be an isotropic phase by heat treatment, the liquid crystal layer is irradiated with light so as to perform polymer stabilization treatment on the liquid crystal layer, and an alignment state of the liquid crystal layer is changed from an isotropic phase to a blue phase in the light irradiation. Thus, a liquid crystal display device which suppresses a defect which shows an alignment state other than a blue phase (an alignment defect) is manufactured.