发明授权
- 专利标题: Tin free silyl-terminated polymers
- 专利标题(中): 无锡甲硅烷基封端的聚合物
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申请号: US13704162申请日: 2011-06-29
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公开(公告)号: US08877885B2公开(公告)日: 2014-11-04
- 发明人: Kamesh R. Vyakaranam , Ling Zhang , William A. Koonce , Juan Carlos Medina , Ganesh Kailasam , Rajat Duggal , Nathan Wilmot
- 申请人: Kamesh R. Vyakaranam , Ling Zhang , William A. Koonce , Juan Carlos Medina , Ganesh Kailasam , Rajat Duggal , Nathan Wilmot
- 申请人地址: US MI Midland
- 专利权人: Dow Global Technologies LLC
- 当前专利权人: Dow Global Technologies LLC
- 当前专利权人地址: US MI Midland
- 国际申请: PCT/US2011/042355 WO 20110629
- 国际公布: WO2012/003212 WO 20120105
- 主分类号: C08G18/20
- IPC分类号: C08G18/20
摘要:
Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.
公开/授权文献
- US20130096252A1 TIN FREE SILYL-TERMINATED POLYMERS 公开/授权日:2013-04-18
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