发明授权
- 专利标题: Process of melt-spinning polyacrylonitrile fiber
- 专利标题(中): 熔融纺丝聚丙烯腈纤维的工艺
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申请号: US13262620申请日: 2010-01-11
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公开(公告)号: US08906278B2公开(公告)日: 2014-12-09
- 发明人: Muhuo Yu , Huaiping Rong , Keqing Han , Zhaohua Wang , Yiwei Zhang , Yincai Tian , Qinli Dong , Xi Zhao , Hui Zhang
- 申请人: Muhuo Yu , Huaiping Rong , Keqing Han , Zhaohua Wang , Yiwei Zhang , Yincai Tian , Qinli Dong , Xi Zhao , Hui Zhang
- 申请人地址: CN Shanghai
- 专利权人: Donghua University
- 当前专利权人: Donghua University
- 当前专利权人地址: CN Shanghai
- 代理机构: Nixon Peabody LLP
- 代理商 Joseph Bach, Esq.
- 优先权: CN200910048603 20090331; CN200910052721 20090609; CN200910053212 20090617; CN200910195794 20090917; CN200910198444 20091106
- 国际申请: PCT/CN2010/000036 WO 20100111
- 国际公布: WO2010/111882 WO 20101007
- 主分类号: D01D5/12
- IPC分类号: D01D5/12 ; D01D7/00 ; D01D10/06 ; B82Y30/00 ; D02J1/22 ; D01D5/06 ; D01F1/02 ; D01F6/18 ; D01F9/22
摘要:
Processes for producing carbon fiber, the filament thereof and pre-oxidized fiber are provided. In one embodiment, the gel spinning of polyacrylonitrile filament is achieved by using small-molecule gelling agent, and the carbon fiber obtained thereby is increased by 15% to 40% in tensile strength and by 20% to 35% in toughness. In another embodiment, the melt spinning process of polyacrylonitrile is conducted by using imidazole type ion liquid as plasticizer, the process reduces environment pollution, is suitable for industrial production and the fiber produced thereby is improved in its strength. In yet another embodiment, polyacrylonitrile pre-oxidized fiber is produced by melt spinning, so low cost and controllable pre-oxidization of polyacrylonitrile can be achieved. In a further embodiment, high strength carbon fiber is manufactured by using polymer thickening agent. In another further embodiment, low cost and controllable pre-oxidization of polyacrylonitrile is achieved by conducting pre-oxidization before spinning, minimizing skin-core structure, so as to produce high performance carbon fiber, and reduce the production cost of carbon fiber greatly.
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