Invention Grant
- Patent Title: Tungsten oxide processing
- Patent Title (中): 氧化钨加工
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Application No.: US14136200Application Date: 2013-12-20
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Publication No.: US08951429B1Publication Date: 2015-02-10
- Inventor: Jie Liu , Xikun Wang , Seung Park , Mikhail Korolik , Anchuan Wang , Nitin K. Ingle
- Applicant: Applied Materials, Inc.
- Applicant Address: US CA Santa Clara
- Assignee: Applied Materials, Inc.
- Current Assignee: Applied Materials, Inc.
- Current Assignee Address: US CA Santa Clara
- Agency: Kilpatrick Townsend & Stockton LLP
- Main IPC: B44C1/22
- IPC: B44C1/22 ; C23F1/00 ; C23F3/00 ; H01J37/32

Abstract:
Methods of selectively etching tungsten oxide relative to tungsten, silicon oxide, silicon nitride and/or titanium nitride are described. The methods include a remote plasma etch using plasma effluents formed from a fluorine-containing precursor in combination with ammonia (NH3). Plasma effluents from the remote plasma are flowed into a substrate processing region where the plasma effluents react with the tungsten oxide. The plasmas effluents react with exposed surfaces and selectively remove tungsten oxide while very slowly removing other exposed materials. Increasing a flow of ammonia during the process removes a typical skin of tungsten oxide having higher oxidation coordination number first and then selectively etching lower oxidation tungsten oxide. In some embodiments, the tungsten oxide etch selectivity results partly from the presence of an ion suppression element positioned between the remote plasma and the substrate processing region.
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