Invention Grant
- Patent Title: Bulk sulfidic mixed metal catalyst and methods for its manufacture and use in converting syngas to alcohol
- Patent Title (中): 散装硫化物混合金属催化剂及其合成气转化成酒精的方法
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Application No.: US13203845Application Date: 2010-03-05
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Publication No.: US08980782B2Publication Date: 2015-03-17
- Inventor: Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
- Applicant: Stephan Janbroers , Bob Gerardus Oogjen , Frans Lodewijk Plantenga , Harmannus Willem Homan Free , Sona Eijsbouts-Spickova , Edgar Evert Steenwinkel , Edwin Nuberg
- Applicant Address: BE
- Assignee: Albemarle Europe SPRL
- Current Assignee: Albemarle Europe SPRL
- Current Assignee Address: BE
- Agent Nathan C. Dunn; James A. Jubinsky; Marcy M. Hoefling
- International Application: PCT/EP2010/052822 WO 20100305
- International Announcement: WO2010/100256 WO 20100910
- Main IPC: B01J27/051
- IPC: B01J27/051 ; B01J23/887 ; B01J37/00 ; B01J37/20 ; C07C29/151

Abstract:
A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.
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