公开(公告)号：US20110319505A1

公开(公告)日：2011-12-29

申请号：US13203845

申请日：2010-03-05

Applicant: Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

Inventor： Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

IPC: C07C27/00 ,  B01J27/051

CPC classification number: B01J27/0515 ,  B01J23/8872 ,  B01J37/0009 ,  B01J37/20 ,  C07C29/1518 ,  Y02P20/52 ,  C07C31/08 ,  C07C31/04

Abstract: A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.

Abstract translation: 硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。 所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量 在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。 还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。

公开(公告)号：US08980782B2

公开(公告)日：2015-03-17

申请号：US13203845

申请日：2010-03-05

Applicant: Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

Inventor： Stephan Janbroers ,  Bob Gerardus Oogjen ,  Frans Lodewijk Plantenga ,  Harmannus Willem Homan Free ,  Sona Eijsbouts-Spickova ,  Edgar Evert Steenwinkel ,  Edwin Nuberg

IPC: B01J27/051 ,  B01J23/887 ,  B01J37/00 ,  B01J37/20 ,  C07C29/151

CPC classification number: B01J27/0515 ,  B01J23/8872 ,  B01J37/0009 ,  B01J37/20 ,  C07C29/1518 ,  Y02P20/52 ,  C07C31/08 ,  C07C31/04

Abstract: A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.

Abstract translation: 硫化钴 - 钼体积催化剂前体以形成本体硫化醇合成催化剂的方法。 所述方法步骤包括使氧化体钴钴钼催化剂前体与一定量的含硫化合物接触，所述含硫化合物的量在约或约10摩尔硫/每摩尔金属的一个或多个温度下或过量 在基本上不加入氢气的介质中约300℃，以便形成硫化体积的钴 - 钼催化剂产物。 还描述了形成催化剂前体的方法，使用催化剂产物和催化剂产物本身生产醇的方法。