Solutions and Catalysts Comprising Group VI Metal, Group VIII Metal, Phosphorus and An Additive
    1.
    发明申请
    Solutions and Catalysts Comprising Group VI Metal, Group VIII Metal, Phosphorus and An Additive 有权
    包括VI族金属,VIII族金属,磷和添加剂的溶液和催化剂

    公开(公告)号:US20120145600A1

    公开(公告)日:2012-06-14

    申请号:US13391336

    申请日:2010-08-24

    Abstract: This invention provides a process for forming a solution composition, which process comprises forming a primary solution by bringing together, in an aqueous medium, i) at least one phosphorus compound, ii) at least one Group VI metal compound, iii) at least one Group VIII metal compound, and iv) an additive which is a) tetraethylene glycol, b) polyethylene glycol having an average molecular weight in the range of about 200 to about 400, c) a mixture of tetraethylene glycol and polyethylene glycol having an average molecular weight in the range of about 200 to about 400, or d) a mixture of (1) tetraethylene glycol and/or polyethylene glycol having an average molecular weight in the range of about 200 to about 400 and (2) one or more of monoethylene glycol, diethylene glycol, and triethylene glycol. The molar ratio of additive to the total moles of Group VI metal and Group VIII metal is above 0.30:1, and the atomic ratio of phosphorus to Group VI metal is at least about 0.33:1. Optionally, the primary solution is heated at a temperature above about 40° C. to form a heated solution. The heated solution is optionally cooled to form a cooled solution. Also provided are compositions formed by such processes, processes for forming catalyst compositions from these compositions, and catalyst compositions formed by these processes.

    Abstract translation: 本发明提供一种形成溶液组合物的方法,该方法包括通过在水性介质中混合形成初级溶液,i)至少一种磷化合物,ii)至少一种VI族金属化合物,iii)至少一种 VIII族金属化合物,和iv)a)四乙二醇,b)平均分子量在约200至约400范围内的聚乙二醇的添加剂,c)四甘醇和聚乙二醇的混合物,其平均分子量 重量在约200至约400的范围内,或d)平均分子量在约200至约400范围内的(1)四甘醇和/或聚乙二醇的混合物,和(2)一种或多种单乙烯 乙二醇,二甘醇和三甘醇。 VI族金属和VIII族金属的添加剂与总摩尔数的摩尔比大于0.30:1,磷与Ⅵ族金属的原子比为至少约0.33:1。 任选地,将主溶液在高于约40℃的温度下加热以形成加热溶液。 加热的溶液任选地冷却以形成冷却的溶液。 还提供了通过这些方法形成的组合物,由这些组合物形成催化剂组合物的方法,以及由这些方法形成的催化剂组合物。

    Bulk Hydroprocessing Catalyst Comprising A Group VIII Metal And Molybdenum, Preparation And Use Thereof
    5.
    发明申请
    Bulk Hydroprocessing Catalyst Comprising A Group VIII Metal And Molybdenum, Preparation And Use Thereof 有权
    包含VIII族金属和钼的大量加氢催化剂,其制备和使用

    公开(公告)号:US20090139904A1

    公开(公告)日:2009-06-04

    申请号:US12091328

    申请日:2006-10-25

    Abstract: The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal (relative to the total amount of Group VIB metals) and comprising a Group V metal in an amount less than 10 mole % (relative to the total of the Group VIB metals), which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, preferably below 450° C. and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61° 2θ. Preferably, the main reflections have a full width at half maximum (FWHM) of less than 2.5. The invention further relates to a process for the manufacture of the bulk catalyst, to the corresponding sulphided bulk catalyst and to the use of said catalyst or sulphided catalyst in the hydroprocessing, in particular the hydrodesulphurisation and hydrodenitrogenation, of a hydrocarbon feedstock.

    Abstract translation: 本发明涉及一种本体催化剂,其包含至少60重量%的包含一种或多种第VIII族金属和VIB族金属钼的金属氧化物颗粒,其包含小于10摩尔%的第二族VIB金属(相对于VIB族的总量) 金属),并且包含少于10摩尔%(相对于第VIB族金属的总量)的第V族金属,该体积催化剂在低于六方晶系亚稳晶体结构变为不活泼的温度的温度下被煅烧 晶体结构,优选低于450℃,并且该体积催化剂具有亚稳态六方晶相,其特征在于具有在33-35和58-61°2θ之间的反射的X射线衍射图。 优选地,主反射具有小于2.5的半高宽(FWHM)。 本发明还涉及一种用于制造本体催化剂的方法,相应的硫化体积催化剂以及所述催化剂或硫化催化剂在烃原料的加氢处理,特别是加氢脱硫和加氢脱氮中的用途。

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