发明授权
- 专利标题: Lithium titanate crystal structure, composite of lithium titanate crystal structure and carbon, method of production thereof, and electrode and electrochemical element employing said composite
- 专利标题(中): 钛酸锂晶体结构,钛酸锂晶体结构和碳的复合物,其制造方法,以及使用所述复合材料的电极和电化学元件
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申请号: US13696053申请日: 2011-05-02
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公开(公告)号: US09005814B2公开(公告)日: 2015-04-14
- 发明人: Katsuhiko Naoi , Wako Naoi , Shuichi Ishimoto , Kenji Tamamitsu
- 申请人: Katsuhiko Naoi , Wako Naoi , Shuichi Ishimoto , Kenji Tamamitsu
- 申请人地址: JP Tokyo
- 专利权人: Nippon Chemi-Con Corporation
- 当前专利权人: Nippon Chemi-Con Corporation
- 当前专利权人地址: JP Tokyo
- 优先权: JP2010-106052 20100504
- 国际申请: PCT/JP2011/002530 WO 20110502
- 国际公布: WO2011/138866 WO 20111110
- 主分类号: H01M4/13
- IPC分类号: H01M4/13 ; H01M4/485 ; B82Y30/00 ; B82Y40/00 ; C01B31/02 ; C01G23/00 ; H01M4/131 ; H01M4/36 ; H01M4/587 ; H01G9/035 ; H01G11/06 ; H01G11/50 ; H01G11/24 ; H01G11/30 ; H01G11/36
摘要:
Highly dispersed lithium titanate crystal structures having a thickness of few atomic layers level and the two-dimensional surface in a plate form are supported on carbon nanofiber (CNF). The lithium titanate crystal structure precursors and CNF that supports these are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The mass ratio between the lithium titanate crystal structure and carbon nanofiber is preferably between 75:25 and 85:15. The carbon nanofiber preferably has an external diameter of 10-30 nm and an external specific surface area of 150-350 cm2/g. This composite is mixed with a binder and then molded to obtain an electrode, and this electrode is employed for an electrochemical element.
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