发明授权
US09079159B2 Olefin metathesis process using a treated tungsten oxide catalyst
有权
使用经处理的氧化钨催化剂的烯烃复分解方法
- 专利标题: Olefin metathesis process using a treated tungsten oxide catalyst
- 专利标题(中): 使用经处理的氧化钨催化剂的烯烃复分解方法
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申请号: US13086671申请日: 2011-04-14
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公开(公告)号: US09079159B2公开(公告)日: 2015-07-14
- 发明人: Christopher P Nicholas , Mark A. Krawczyk , Kristoffer E. Popp , Jennifer F. Abrahamian
- 申请人: Christopher P Nicholas , Mark A. Krawczyk , Kristoffer E. Popp , Jennifer F. Abrahamian
- 申请人地址: US IL Des Plaines
- 专利权人: UOP LLC
- 当前专利权人: UOP LLC
- 当前专利权人地址: US IL Des Plaines
- 主分类号: C07C6/04
- IPC分类号: C07C6/04 ; C07C6/02 ; B01J37/18 ; B01J37/08 ; B01J23/30 ; B01J37/02 ; B01J38/04
摘要:
A process for olefin metathesis is disclosed. The process involves contacting a feedstock comprising a first olefin and a second olefin having a carbon number at least two greater than that of the first olefin with a catalyst comprising a tungsten component on a refractory oxide support, e.g. silica at metathesis conditions to provide a product olefin having an intermediate carbon number between that of the first and second olefin. The catalyst is characterized in that it is first pretreated with hydrogen followed by treatment with ethylene.
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