A low friction coating for an internal combustion engine and a method of forming a low friction surface on at least one of the engine's friction-sensitive components. In one form, a solid lubricant precursor additive is combined with motor oil such that upon work being performed on the combination by adjacently-interacting engine components, the solid lubricant tribochemically reacts to form a friction-reducing coating or film. In one preferred form, the coating or film is triboformed on a cylinder bore or a liner configured to fit within the bore. The reciprocating movement between the cylinder or liner and a piston and/or piston rings promotes in-situ formation of the layer after the engine has already been manufactured rather than during engine fabrication or assembly.