In accordance with the present invention, there is provided a fluid or liquid barrier packing system which is adapted to minimize VOC emissions, while also providing live-loading and continuous load monitoring functions. The components of the packing system (including the liquid barrier) are adapted to be installed in a traditional stuffing box of a valve utilizing a top entry method, and without the necessity of having to inject the liquid through any side ports of the valve. The packing system reduces leakage levels as required by low emission leakage specifications by creating a reverse osmosis effect, limiting the diffusivity of a gas through the packing elements of the system. Thus, the packing system of the present invention provides a simplified method to load and monitor a barrier in the stuffing box of the valve to slightly higher pressure than processed fluid pressure.