A photo-electric device including a photoelectric conversion layer and a plurality of electrodes is provided. The photoelectric conversion layer includes a plurality of inversed pyramid shaped recesses and a plurality of a pyramids, wherein each of the inversed pyramid shaped recesses has at least three first reflection sidewalls, each of the pyramids is located in one of the inversed pyramid shaped recesses respectively, each of the pyramids has at least three second reflection sidewalls, and none of the first reflection sidewall and the second reflection sidewall is located in a same plane. The electrodes are electrically connected to the photoelectric conversion layer.