Invention Grant
- Patent Title: Polymer, process and composition
- Patent Title (中): 聚合物,工艺和组成
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Application No.: US14376232Application Date: 2013-02-04
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Publication No.: US09255171B2Publication Date: 2016-02-09
- Inventor: Tijs Nabuurs , Gerardus Cornelis Overbeek , Jeffrey Stubbs , Matthew Stewart Gebhard
- Applicant: DSM IP ASSETS B.V.
- Applicant Address: NL Heerlen
- Assignee: DSM IP ASSETS B.V.
- Current Assignee: DSM IP ASSETS B.V.
- Current Assignee Address: NL Heerlen
- Agency: Nixon & Vanderhye P.C.
- Priority: EP12153838 20120203; EP12153839 20120203; EP12153840 20120203; EP12153842 20120203; EP12175782 20120710; EP12175784 20120710; EP12175785 20120710; EP12175786 20120710; EP12175788 20120710
- International Application: PCT/EP2013/052172 WO 20130204
- International Announcement: WO2013/113936 WO 20130808
- Main IPC: C08F301/00
- IPC: C08F301/00 ; C08F220/14 ; C08F222/14 ; C08F293/00 ; C09D153/00 ; C08F220/06 ; C09D133/02 ; C09D133/12 ; C09D135/02 ; C08L33/02 ; C08L33/12 ; B05D3/02 ; B05D3/06 ; B05D3/10 ; C08F22/10 ; C08F22/38 ; C08F26/06 ; C09D133/14 ; C08L33/10 ; C08L51/00 ; C08L67/08 ; C08L75/04 ; C09D133/10 ; C09D151/00 ; C09D167/08 ; C09D175/04 ; C08L35/02 ; C09D133/08 ; C09D125/14 ; C09D175/08 ; C08F222/04 ; C08L75/00 ; C08F220/18

Abstract:
There are described q oligomer-polymer composition [optionally substantially free of styrene ( =20 wt-% of a higher itaconate diester (preferably dibutyl itaconate—DBI); (b) less than 23 wt-% acid monomer but also sufficient to have an acid value less than 150 mg KOH/g of polymer, (c) optionally with less than 50 wt-% of other itaconate monomers, and (d) optionally less than 77 wt-% of other monomers not (a) to (c). The DBI may be biorenewable. One embodiment is an aqueous dispersion of vinyl sequential polymer of two phases: A) 40 to 90 wt-% of a vinyl polymer A with Tg from −50 to 30° C.; and B) 10 to 60 wt-% of a vinyl polymer B with Tg from 50 to 130° C.; where DBI is used to prepare A and/or B and polymer A has from 0.1 to 10 wt-% of at least one acid-functional olefinically unsaturated monomer. Another embodiment is an aqueous polymer coating composition of a vinyl oligomer C of Mw from 1,000 to 150,000 g/mol and an acid value>5 mgKOH/g; and a vinyl polymer D of Mw>=80,000 g/mol and an acid value
Public/Granted literature
- US20150017460A1 POLYMER, PROCESS AND COMPOSITION Public/Granted day:2015-01-15
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