Invention Grant
- Patent Title: Method for reducing mercaptans in hydrocarbons
- Patent Title (中): 降低碳氢化合物中硫醇的方法
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Application No.: US13281114Application Date: 2011-10-25
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Publication No.: US09296956B2Publication Date: 2016-03-29
- Inventor: Lin Li , Zunqing He , Zhen Zhou , King T. Ng , Paul E. Hajdu
- Applicant: Lin Li , Zunqing He , Zhen Zhou , King T. Ng , Paul E. Hajdu
- Applicant Address: US CA San Ramon
- Assignee: Chevron U.S.A. Inc.
- Current Assignee: Chevron U.S.A. Inc.
- Current Assignee Address: US CA San Ramon
- Agency: Gregory L. Porter, Andrews Kurth LLP
- Agent Parul Anderson
- Main IPC: C10G27/02
- IPC: C10G27/02 ; C10G17/07 ; C10G19/02 ; C10G53/10 ; C10G53/12

Abstract:
A method for reducing mercaptan concentration in a crude oil is disclosed. The method comprises contacting the crude with a treating solution comprising a hypochlorite solution, whereby the mercaptan sulfur is oxidized and converted to at least one sulfur oxoacid or salt thereof, yielding a treated crude oil having less than 50 ppm mercaptan sulfur and residual organic chloride. The treated crude oil containing residual organic chloride is brought in contact with a caustic solution at a molar ratio of caustic to chloride of 0.1:1 to 50:1, generating an upgraded crude oil with less than 10 ppm organic chloride. In one embodiment, the spent treating solution is recycled to form a regenerated hypochlorite stream for use in the treatment solution.
Public/Granted literature
- US20120103872A1 METHOD FOR REDUCING MERCAPTANS IN HYDROCARBONS Public/Granted day:2012-05-03
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