A hybrid carbon black, a coating composition, and a shielding material employing the same are provided. The hybrid carbon black includes a core of carbon black, and a cross-linked network polymer film covering the whole surface of the carbon black overall. In particular, the carbon black core has a mass fractal dimension between 2 and 3 and a surface fractal dimension between 2 and 2.5, and the cross linking network polymer film includes a product obtained by crosslinking a composition including a styrene monomer and a divinylbenzene monomer.