Method of forming copper wiring

Invention Grant

US09362166B2 Method of forming copper wiring 有权

Title translation: 形成铜线的方法

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Patent Title: Method of forming copper wiring
Patent Title (中): 形成铜线的方法
Application No.: US14642331

Application Date: 2015-03-09
Publication No.: US09362166B2

Publication Date: 2016-06-07
Inventor: Tadahiro Ishizaka , Takashi Sakuma , Osamu Yokoyama , Kenji Matsumoto , Peng Chang , Hiroyuki Nagai
Applicant: TOKYO ELECTRON LIMITED
Applicant Address: JP Tokyo
Assignee: TOKYO ELECTRON LIMITED
Current Assignee: TOKYO ELECTRON LIMITED
Current Assignee Address: JP Tokyo
Agency: Nath, Goldberg & Meyer
Agent Jerald L. Meyer
Priority: JP2014-053934 20140317
Main IPC: H01L21/4763
IPC: H01L21/4763 ; H01L21/768 ; H01L21/285 ; H01L23/532

Abstract:

A method of forming a copper wiring buried in a recess portion of a predetermined pattern formed in an interlayer insulation layer of a substrate is disclosed. The method includes: forming a manganese oxide film at least on a surface of the recess portion, the manganese oxide film serving as a self-aligned barrier film through reaction with the interlayer insulation layer; performing hydrogen radical treatment with respect to a surface of the manganese oxide film; placing a metal more active than ruthenium on the surface of the manganese oxide film after the hydrogen radical treatment; forming a ruthenium film on the surface where the metal more active than ruthenium is present; and forming a copper film on the ruthenium film by physical vapor deposition (PVD) to bury the copper film in the recess portion.

Abstract(Chinese):

公开了一种埋设在衬底的层间绝缘层中形成的预定图案的凹部中的铜布线的形成方法。该方法包括：通过与层间绝缘层反应，至少在凹部的表面上形成氧化锰膜，氧化锰膜作为自对准阻挡膜; 相对于氧化锰膜的表面进行氢自由基处理; 在氧自由基处理之后，将比钌更金属的氧化物膜置于氧化锰膜的表面上; 在其上存在比钌更有活性的金属的表面上形成钌膜; 并通过物理气相沉积（PVD）在钌膜上形成铜膜以将铜膜埋入凹部中。

Public/Granted literature

US20150262872A1 METHOD OF FORMING COPPER WIRING Public/Granted day:2015-09-17

Information query

Espacenet

IPC分类:

H	电学
H01	基本电气元件
H01L	半导体器件；其他类目中不包括的电固体器件（使用半导体器件的测量入G01；一般电阻器入H01C；磁体、电感器、变压器入H01F；一般电容器入H01G；电解型器件入H01G9/00；电池组、蓄电池入H01M；波导管、谐振器或波导型线路入H01P；线路连接器、汇流器入H01R；受激发射器件入H01S；机电谐振器入H03H；扬声器、送话器、留声机拾音器或类似的声机电传感器入H04R；一般电光源入H05B；印刷电路、混合电路、电设备的外壳或结构零部件、电气元件的组件的制造入H05K；在具有特殊应用的电路中使用的半导体器件见应用相关的小类）
H01L21/00	专门适用于制造或处理半导体或固体器件或其部件的方法或设备
H01L21/02	.半导体器件或其部件的制造或处理
H01L21/04	..至少具有一个跃变势垒或表面势垒的器件，例如PN结、耗尽层、载体集结层
H01L21/34	...具有H01L21/06，H01L21/16及H01L21/18各组不包含的或有或无杂质，例如掺杂材料的半导体的器件
H01L21/46	....用H01L21/36至H01L21/428各组不包含的方法或设备处理半导体材料的（在半导体材料上制作电极的入H01L21/44）
H01L21/461	.....改变半导体材料的表面物理特性或形状的，例如腐蚀、抛光、切割
H01L21/4763	......非绝缘层的沉积，例如绝缘层上的导电层、电阻层；这些层的后处理（电极的制造入H01L21/28）