Integrated circuits with a diffusion barrier layers, and processes for preparing integrated circuits including diffusion barrier layers are provided herein. An exemplary integrated circuit includes a semiconductor substrate comprising a semiconductor material, a compound gate dielectric overlying the semiconductor substrate, and a gate electrode overlying the compound gate dielectric. In this embodiment, the compound gate dielectric includes a first dielectric layer, a diffusion barrier layer overlying the first dielectric layer; and a second dielectric layer overlying the diffusion barrier layer; wherein the diffusion barrier layer is made of a material that is less susceptible to diffusion of the semiconductor material than the first dielectric layer, less susceptible to diffusion of oxygen than the second dielectric layer, or both.