发明授权
US09518133B2 Hydrophilic polyacrylic acid (salt) resin and manufacturing method thereof
有权
亲水性聚丙烯酸(盐)树脂及其制造方法
- 专利标题: Hydrophilic polyacrylic acid (salt) resin and manufacturing method thereof
- 专利标题(中): 亲水性聚丙烯酸(盐)树脂及其制造方法
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申请号: US13148359申请日: 2010-02-08
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公开(公告)号: US09518133B2公开(公告)日: 2016-12-13
- 发明人: Shinichi Fujino , Satoshi Matsumoto , Kunihiko Ishizaki
- 申请人: Shinichi Fujino , Satoshi Matsumoto , Kunihiko Ishizaki
- 申请人地址: JP Osaka
- 专利权人: NIPPON SHOKUBAI CO., LTD.
- 当前专利权人: NIPPON SHOKUBAI CO., LTD.
- 当前专利权人地址: JP Osaka
- 代理机构: Wenderoth, Lind & Ponack, L.L.P.
- 优先权: JP2009-026807 20090206; JP2009-026808 20090206
- 国际申请: PCT/JP2010/051822 WO 20100208
- 国际公布: WO2010/090322 WO 20100812
- 主分类号: C08F20/02
- IPC分类号: C08F20/02 ; C08F20/06 ; C08F2/44 ; C08F220/06
摘要:
The physical properties of a water-absorbing resin with low residual monomer content are improved or stabilized, without sacrifices in productivity, production cost, stability, etc. Provided is a water-absorbing resin with low residual monomer content and excellent whiteness, wherein a water-absorbing resin consumed in large quantities in disposable diapers, etc., is preferably a sustainable and renewable water-absorbing resin that does not require excessive purification of the acrylic acid, particularly acrylic acids derived from non-fossil sources, that is the starting material of the water-absorbing resin. Disclosed is a method of manufacturing a hydrophilic polyacrylic acid (salt) resin, which is a method of manufacturing a water-absorbing polyacrylic acid resin that comprises a step in which a monomer is prepared from acrylic acid, a step in which said monomer is polymerized, and a step in which the resulting hydrous gel is dried. The polymerization is performed such that the content of hydroxypropionic acid (salt) in the monomer is 2000 ppm or less and/or the content of saturated organic carboxylic acid in the monomer is 2% by mass or less, and at least a portion of the saturated organic carboxylic acid is volatilized during and after the drying step.
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