Invention Grant
- Patent Title: Process for producing a semi-aromatic semi-crystalline polyamide
- Patent Title (中): 半芳族半结晶聚酰胺的制备方法
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Application No.: US14899404Application Date: 2014-06-16
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Publication No.: US09556310B2Publication Date: 2017-01-31
- Inventor: Rudy Rulkens , Eric Grolman , Geert Adelina Rudolf Vanden Poel , Renier Henricus Maria Kierkels , Theo Joseph Cuypers , Constantine D. Papaspyrides , Athanasios D. Porfyris
- Applicant: DSM IP ASSETS B.V.
- Applicant Address: NL Heerlen
- Assignee: DSM IP ASSETS B.V.
- Current Assignee: DSM IP ASSETS B.V.
- Current Assignee Address: NL Heerlen
- Agency: Nixon & Vanderhye P.C.
- Priority: EP13172829 20130619
- International Application: PCT/EP2014/062513 WO 20140616
- International Announcement: WO2014/202506 WO 20141224
- Main IPC: C08G69/30
- IPC: C08G69/30 ; C08G69/26 ; C08L77/00 ; C08L77/06

Abstract:
The invention relates to a process for the preparation of semi-crystalline semi-aromatic polyamide by direct solid-state polymerization of a diamine-dicarboxylic acid salt, comprising steps of (a) providing at least two salts of terephthalic acid and diamine, wherein each of these diamine/terephthalic acid salts is in solid state and has a melting temperature of at least Tx, wherein Tx is at least 260° C.; (b) preparing a mixture of the diamine/terephthalic acid salts, while retaining the salts in solid state; and (c) heating the mixture obtained from step (b) in the solid state to a temperature (T-c) in the range from 200° C. to 260° C., under a pressure below the saturation vapor pressure of water at said temperature, thereby condensing and polymerizing the salts and forming a semi-crystalline semi-aromatic polyamide in solid form.
Public/Granted literature
- US20160137781A1 PROCESS FOR PRODUCING A SEMI-AROMATIC SEMI-CRYSTALLINE POLYAMIDE Public/Granted day:2016-05-19
Information query
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